ArticleScientific reports2024
Sustainable conversion of polyethylene plastic bottles into terephthalic acid, synthesis of coated MIL-101 metal-organic framework and catalytic degradation of pollutant dyes.
Article in Scientific reports, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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2 citing papers in PubMed.
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4 authors.
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Abstract
Persistent environmental colored compounds, resistant to biodegradation, accumulate and harm eco-systems. Developing effective methods to break down these pollutants is crucial. This study introduces Ag-MIL-101 (Ag-MIL-101) as a composite and reusable catalyst that efficiently degrades specific colored organic pollutants (COPs) like Methylene blue (MB), 4-Nitrophenol (4-NP), and 4-Nitroaniline (4-NA) using sodium borohydride at room temperature. The MIL-101 was synthesized using Terephthalic acid (TPA) derived from the degradation of Polyethylene Terephthalate (PET) plastic waste, with the assistance of zinc chloride. To further investigation, the kinetics of degradation reaction was studied under optimized conditions in the presence of Ag-MIL-101 as catalyst. Our results demonstrated the remarkable efficiency of the degradation process, with over 93% degradation achieved within just 8 min. The catalyst was characterized using FTIR, XRD, FESEM, and TEM. In this study, the average particle size of Ag-MIL-101 was determined using SEM and XRD analysis. These methods allow us to accurately and precisely determine the particle size. We determined the reaction rate constants for the degradation of each COP using a pseudo first-order kinetic equation, with values of 0.585, 0.597 and 0.302 min
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