ArticleACS nano2024
Observation of SOMO-HOMO Inversion in a Neutral Polycyclic Conjugated Hydrocarbon.
Article in ACS nano, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Self-Assembly and Electronic States of an Electron Acceptor Molecule on a Metal Substrate.ACS nano · 2026Article
- Designing Pancake-Bonded Heterodimers for Scanning Probe Microscopy.The journal of physical chemistry. A · 2026Article
- An sp-spNature communications · 2025Article
- Tip-Induced Nitrene Generation.ACS nano · 2025Article
- Synthesis of a Stable Radical Cation of Bis-Tert-Butyl Ethylenedioxythiophene and its Application as a Dopant in Organic Semiconductors.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Multireference Theory of Scanning Tunneling Spectroscopy Beyond One-Electron Molecular Orbitals: Can We Image Molecular Orbitals?Journal of the American Chemical Society · 2025Article
- Distance and Voltage Dependence of Orbital Density Imaging Using a CO-Functionalized Tip in Scanning Tunneling Microscopy.ACS nano · 2025Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We report the generation of a nonbenzenoid polycyclic conjugated hydrocarbon, which consists of a biphenyl moiety substituted by indenyl units at the 4,4' positions, on ultrathin sodium chloride films by tip-induced chemistry. Single-molecule characterization by scanning tunneling and atomic force microscopy reveals an open-shell biradical ground state with a peculiar electronic configuration wherein the singly occupied molecular orbitals (SOMOs) are lower in energy than the highest occupied molecular orbital (HOMO).
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.