Evidence map›Paper›PMID 38824127›Full record

ArticleNature communications2024

Revealing the structural evolution of CuAg composites during electrochemical carbon monoxide reduction.

Di Wang, Hyun Dong Jung, Shikai Liu, Jiayi Chen, Haozhou Yang, Qian He, Shibo Xi, Seoin Back, Lei Wang

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Variations of Alloying Site Density in PdAngewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Di Wang *Department of Chemical and Biomolecular Engineering, College of Design and Engineering, National University of Singapore, Singapore, Singapore.
Hyun Dong Jung *Department of Chemical and Biomolecular Engineering, Institute of Emergent Materials, Sogang University, Seoul, Republic of Korea.ORCID http://orcid.org/0000-0002-9649-5479
Shikai LiuDepartment of Materials Science and Engineering, College of Design and Engineering, National University of Singapore, Singapore, Singapore.
Jiayi ChenDepartment of Chemical and Biomolecular Engineering, College of Design and Engineering, National University of Singapore, Singapore, Singapore.
Haozhou YangDepartment of Chemical and Biomolecular Engineering, College of Design and Engineering, National University of Singapore, Singapore, Singapore.ORCID http://orcid.org/0000-0002-8426-0541
Qian HeDepartment of Materials Science and Engineering, College of Design and Engineering, National University of Singapore, Singapore, Singapore. heqian@nus.edu.sg.ORCID http://orcid.org/0000-0003-4891-3581
Shibo XiInstitute of Sustainability for Chemicals, Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), Singapore, Singapore. xi_shibo@isce2.a-star.edu.sg.
Seoin BackDepartment of Chemical and Biomolecular Engineering, Institute of Emergent Materials, Sogang University, Seoul, Republic of Korea. sback@sogang.ac.kr.
Lei WangDepartment of Chemical and Biomolecular Engineering, College of Design and Engineering, National University of Singapore, Singapore, Singapore. wanglei8@nus.edu.sg.ORCID http://orcid.org/0000-0002-1931-7767

Funding

Agency for Science, Technology and Research (A*STAR) U2102d2002National Research Foundation Singapore (National Research Foundation-Prime Minister's office, Republic of Singapore) NRF-NRFF11-2019-0002National Research Foundation Singapore (National Research Foundation-Prime Minister's office, Republic of Singapore) NRF-NRFF13-2021-0007
6 · The paper itself

Abstract

Comprehending the catalyst structural evolution during the electrocatalytic process is crucial for establishing robust structure/performance correlations for future catalysts design. Herein, we interrogate the structural evolution of a promising Cu-Ag oxide catalyst precursor during electrochemical carbon monoxide reduction. By using extensive in situ and ex situ characterization techniques, we reveal that the homogenous oxide precursors undergo a transformation to a bimetallic composite consisting of small Ag nanoparticles enveloped by thin layers of amorphous Cu. We believe that the amorphous Cu layer with undercoordinated nature is responsible for the enhanced catalytic performance of the current catalyst composite. By tuning the Cu/Ag ratio in the oxide precursor, we find that increasing the Ag concentration greatly promotes liquid products formation while suppressing the byproduct hydrogen. CO

Identifiers

PMID38824127
PMCPMC11144262

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.