Evidence map›Paper›PMID 38818072›Full record

ReviewJACS Au2024

Ligand Exchange at Carbon: Synthetic Entry to Elusive Species and Versatile Reagents.

Felix Krischer, Viktoria H Gessner

Abstract readReview
In one paragraph

Review in JACS Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Isolable C-Phosphonio-Boratavinyl Anion.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. "In Situ" Orbital Correlations.Accounts of chemical research · 2026
    Article
  3. The Pyridylketenyl Anion: Entry to Diverse N-Heterocycles.Journal of the American Chemical Society · 2026
    Article
  4. Article
  5. Isolation of Anionic N-Heterocyclic Olefins and Their Versatile Reactivity.Angewandte Chemie (International ed. in English) · 2025
    Article
  6. Article
  7. Conversion of Bestmann Ylide into Carbophosphinocarbene.Angewandte Chemie (International ed. in English) · 2025
    Article
  8. Reactions of RAngewandte Chemie (International ed. in English) · 2025
    Article
  9. A Lead(II) Substituted Triplet Carbene.Journal of the American Chemical Society · 2024
    Article
  10. An Azide-Free Synthesis of Metallodiazomethanes Using Nitrous Oxide.Journal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Felix KrischerFaculty of Chemistry and Biochemistry, Ruhr University Bochum, Universitaetsstrasse 150, 44801 Bochum, Germany.ORCID https://orcid.org/0000-0001-9301-6930
Viktoria H GessnerFaculty of Chemistry and Biochemistry, Ruhr University Bochum, Universitaetsstrasse 150, 44801 Bochum, Germany.ORCID https://orcid.org/0000-0001-6557-2366

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

How different is carbon compared to other elements in the periodic table? Can carbon compounds be regarded as coordination complexes with carbon as the central element undergoing a facile exchange of its ligands? Although carbon clearly plays a special role among the elements of the periodic table, recent studies have drawn parallels between the bonding situation and the reactivity of carbon compounds to transition metal complexes. This Perspective summarizes recent reports about ylidic and zwitterionic compounds that were shown to exhibit ambiguous bonding situations that can be interpreted as donor-acceptor interactions similar to the bond between a metal and a neutral ligand. Based on this conception, ligand exchange reactions prototypical of transition metal complexes were realized at carbon atoms, enabling new synthetic strategies for the synthesis of reactive species and building blocks. In particular, the exchange of N

Identifiers

PMID38818072
PMCPMC11134600

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.