ArticleInorganic chemistry2024
Zintl Clusters as a Platform for Lewis Acid Catalysis.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Isolation of Potassium Bis(amido)diazadipnictogenide Salts.Organometallics · 2026Article
- Reactivity of Tetrel-Functionalized Heptaphosphane Clusters toward Azides.Inorganic chemistry · 2024Article
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3 authors.
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Abstract
Clusters of the main group elements phosphorus and arsenic, commonly categorized as Zintl clusters, have been known for over a century. And, only now is the application of these systems as catalysts for organic synthesis being investigated. In this work, boranes are tethered via an aliphatic linker to Zintl-based clusters and their Lewis acidity is examined experimentally, by the Gutmann-Beckett test and competency in the hydroborative reduction of six organic substrates, as well as computationally, by fluoride ion affinity and hydride ion affinity methods. The effects of tuning the aliphatic linker length, substituents at the boron, and changing the cluster from a seven-atom phosphorus system to a seven-atom arsenic system on reactivity are studied.
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