ArticleChemical science2024
Continuous flow synthesis and post-synthetic conversion of single-crystalline covalent organic frameworks.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Crystalline Framework Electrodes for Hybrid Supercapacitors: Device-Oriented Design From Metal-Organic and Covalent Organic Frameworks to Practical Hybrids.Chemical record (New York, N.Y.) · 2026Review
- Structural Modulation of TpPa‑1 Covalent Organic Framework in Flow Synthesis Guided by Green Chemistry Principles.ACS engineering Au · 2026Article
- Potential of Covalent Organic Framework in Pharmacy and Biomedicine: Influence of Structure on Properties and Applications.ChemMedChem · 2026Review
- Porous Functional Nanomaterials for Continuous Flow Catalysis.Nano-micro letters · 2026Review
- Covalent Organic Frameworks for Photocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Unconventional Fast Room Temperature Synthesis of Covalent Organic Framework Single Crystals Unveiling Precise Structural Insights.Angewandte Chemie (International ed. in English) · 2025Article
- Photons, Excitons, and Electrons in Covalent Organic Frameworks.Journal of the American Chemical Society · 2024Review
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis and scale-up of high quality covalent organic frameworks (COFs) remains a challenge due to slow kinetics of the reversible bond formation and the need for precise control of reaction conditions. Here we report the rapid synthesis of faceted single crystals of two-dimensional (2D) COFs using a continuous flow reaction process. Two imine linked materials were polymerized to the hexagonal CF-TAPB-DMPDA and the rhombic CF-TAPPy-PDA COF, respectively. The reaction conditions were optimized to produce single crystals of micrometer size, which notably formed when the reaction was cooling to room temperature. This indicated a growth mechanism consistent with the fusion of smaller COF particles. The optimized conditions were used to demonstrate the scalability of the continuous approach by synthesizing high quality, faceted COFs at a rate of more than 1 g h
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Registered trials
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