Evidence map›Paper›PMID 38784069›Full record

ArticlePhotochem2022

Awakening a Molecular Mummy: The Inter-and Intramolecular Photochemistry of Pyromellitic Diimides with Alkyl Carboxylates.

Wolfgang H Kramer, Donya Razinoubakht, Gurjit Kaur, Axel Klein, Simon Garbe, Jörg Neudörfl, Sabrina Molitor, Anne Zimmer, Axel G Griesbeck

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Photochem, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Wolfgang H KramerDepartment of Chemistry and Biochemistry, Millsaps College, 1701 North State Street, Jackson, MS 39210, USA.
Donya RazinoubakhtDepartment of Chemistry and Biochemistry, Millsaps College, 1701 North State Street, Jackson, MS 39210, USA.
Gurjit KaurDepartment of Chemistry and Biochemistry, Millsaps College, 1701 North State Street, Jackson, MS 39210, USA.
Axel KleinDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Cologne, Inorganic Chemistry, Greinstr. 6, 50939 Köln, Germany.ORCID 0000-0003-0093-9619
Simon GarbeDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Cologne, Inorganic Chemistry, Greinstr. 6, 50939 Köln, Germany.
Jörg NeudörflDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Cologne, Organic Chemistry, Greinstr. 4, 50939 Köln, Germany.
Sabrina MolitorDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Cologne, Organic Chemistry, Greinstr. 4, 50939 Köln, Germany.
Anne ZimmerDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Cologne, Organic Chemistry, Greinstr. 4, 50939 Köln, Germany.
Axel G GriesbeckDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, University of Cologne, Organic Chemistry, Greinstr. 4, 50939 Köln, Germany.ORCID 0000-0002-6546-3482

Funding

Training and Mentoring Core P20GM103476 · NIGMS · UNIVERSITY OF SOUTHERN MISSISSIPPI · PI MICHAEL R GARRETT · 2012 to 2026
$60.2M
TOUGALOO PROTEOMICSP20RR016476 · NCRR · UNIVERSITY OF SOUTHERN MISSISSIPPI · PI SHEARER, GLEN · 2001 to 2011
$30.4M
NCRR NIH HHS P20 RR016476NIGMS NIH HHS P20 GM103476
6 · The paper itself

Abstract

Pyromellitic acid diimides are not as chemically unreactive as conjecturable (and presupposed) from their numerous applications as electron acceptor units or electron carriers in molecular donor-acceptor dyads or triads. Similar to the corresponding phthalimides, electronically excited pyromellitic diimides oxidize alkyl carboxylates in aqueous solution via intermolecular electron transfer (PET) processes, which eventually results in radical-radical combination products, e.g., the benzylation product

Indexed as

alkylative degradationelectron transferphotodecarboxylationpyromellitic imidesradical ions

Identifiers

PMID38784069
PMCPMC11115379

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.