Impact of self-assembled structure on ionic conductivity of an azobenzene-containing electrolyte.

Shangming He, Zhifan Fang, Dong Liu, Yun Liu, Shichu Yang, Hongfei Wang, Zhihao Shen, Shuangjun Chen, Xing-He Fan

Abstract read

In one paragraph

Article in RSC advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Shangming HeCollege of Materials Science & Engineering, Nanjing Tech University Nanjing 210009 China.ORCID https://orcid.org/0009-0007-2807-2005

Zhifan FangCollege of Materials Science & Engineering, Nanjing Tech University Nanjing 210009 China.ORCID https://orcid.org/0009-0000-7293-461X

Dong LiuBeijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China zshen@pku.edu.cn.ORCID https://orcid.org/0000-0002-3028-0483

Yun LiuBeijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China zshen@pku.edu.cn.ORCID https://orcid.org/0000-0001-6551-9362

Shichu YangBeijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China zshen@pku.edu.cn.ORCID https://orcid.org/0000-0002-3791-2279

Hongfei WangBeijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China zshen@pku.edu.cn.ORCID https://orcid.org/0009-0000-9354-0361

Zhihao ShenBeijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China zshen@pku.edu.cn.ORCID https://orcid.org/0000-0003-2858-555X

Shuangjun ChenCollege of Materials Science & Engineering, Nanjing Tech University Nanjing 210009 China.ORCID https://orcid.org/0000-0002-9162-6142

Xing-He FanBeijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 China zshen@pku.edu.cn.ORCID https://orcid.org/0000-0002-0585-2558

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The type of self-assembled structure has a significant impact on the ionic conductivity of block copolymer or liquid crystalline (LC) ion conductors. In this study, we focus on the effect of self-assembled structures on the ionic conductivity of a non-block copolymer, LC ion conductor, which is a mixture of an azobenzene monomer (NbAzo), pentaerythritol tetre(3-mercapropionate) (PETMP), and a lithium salt, lithium bis(trifluoromethane)sulfonimide (LiTFSI). The self-assembled structures and ionic conductivities of ion conductors having different doping ratios of lithium salt to monomer were examined. With the increase in the doping ratio, the self-assembled structure transforms from lamellae (LAM) to double gyroid (GYR). The effect of self-assembled structure on ionic conductivity was analyzed; it was found that the conductivity of the GYR structure was about 3.6 times that of the LAM one, indicating that obtaining the GYR structure is more effective in improving ionic conductivity.

Identifiers

PMID38765478

DOI10.1039/d4ra02300e

PMCPMC11099987

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.