ArticleScientific reports2024
Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database.
Article in Scientific reports, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
15 citing papers in PubMed.
- Carboxylate-Ligand-Based Coordination Polymers and Metal Complexes: From Structural Diversity and Supramolecular Descriptors to Function-Oriented Design.Molecules (Basel, Switzerland) · 2026Review
- Highly efficient dual-channel doublet emission in lanthanide cerium(III) complex.Light, science & applications · 2026Article
- Diadochic single crystal of an erbium-neodymium nitrate complex.Acta crystallographica. Section E, Crystallographic communications · 2026Article
- Topological isomers in lanthanide-chloranilate coordination polymers: synthesis, structure and CORSC advances · 2026Article
- Metal-Dependent Photodissociation of Hydrazone Photoswitches from Rare-Earth Complexes.Journal of the American Chemical Society · 2026Article
- Electronic Structure, Ligand Effects, and Chemical Reactivity of the Ground and Low-Lying Excited Electronic States of NpOMolecules (Basel, Switzerland) · 2026Article
- Strategies to control the geometry and symmetry around lanthanide centres for tailored luminescence and magnetism.Nature communications · 2026Article
- Emerging trends and structure-activity insights of Schiff base-lanthanide complexes as antibacterial agents.RSC advances · 2026Review
- Seven-Coordinate Lanthanide Bis-Halide Bis-Tetrathiometallate Complexes: A Compelling Platform for Luminescent and Magnetic Properties.Inorganic chemistry · 2026Article
- Investigating the structure and bioactivity of lanthanum coordination compounds.Turkish journal of chemistry · 2026Article
- Polynuclear Complexes of Nd and Dy with NInorganic chemistry · 2025Article
- Article
- Tuning Lanthanide Binding with Phenanthroline-Based Diamides via Electron-Donating and Electron-Withdrawing Groups.The journal of physical chemistry. A · 2025Article
- Potentiometric Studies of the Complexation Properties of Selected Lanthanide Ions with Schiff Base Ligand.International journal of molecular sciences · 2025Article
- On the Importance of Configuration Search to the Predictivity of Lanthanide Selectivity.JACS Au · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
Abstract
Understanding lanthanide coordination chemistry can help develop new ligands for more efficient separation of lanthanides for critical materials needs. The Cambridge Structural Database (CSD) contains tens of thousands of single crystal structures of lanthanide complexes that can serve as a training ground for both fundamental chemical insights and future machine learning and generative artificial intelligence models. This work aims to understand the currently available structures of lanthanide complexes in CSD by analyzing the coordination shell, donor types, and ligand types, from the perspective of rare-earth element (REE) separations. We obtain four sets of lanthanide complexes from CSD: Subset 1, all Ln-containing complexes (49472 structures); Subset 2, mononuclear Ln complexes (27858 structures); Subset 3, mononuclear Ln complexes without cyclopentadienyl ligands (Cp) (26156 structures); Subset 4, Ln complexes with at least one 1,10-phenanthroline (phen) or its derivative as a coordinating ligand (2226 structures). The subsequent analysis of lanthanide complexes in these subsets examines the trends in coordination numbers and first shell distances as well as identifies and characterizes the ligands and donor groups. In addition, examples of Ln-complexes with commercially available complexants and phen-based ligands are interrogated in detail. This systematic investigation lays the groundwork for future data-driven ligand designs for REE separations based on the structural insights into the lanthanide coordination chemistry.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.