ArticleChemical science2024
Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Structural dynamics of melting and glass formation in a two-dimensional hybrid perovskite.Nature communications · 2025Article
- Engineering a Meltable MOF to Tune Liquid Transition and Promote Coenzyme Regeneration.Angewandte Chemie (International ed. in English) · 2025Article
- Glass Transition, Liquid Dynamics, and Thermal Degradation in 2D Hybrid Halide Perovskites.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
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Authors and funding
21 authors.
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Abstract
Hybrid organic-inorganic perovskites (HOIPs) occupy a prominent position in the field of materials chemistry due to their attractive optoelectronic properties. While extensive work has been done on the crystalline materials over the past decades, the newly reported glasses formed from HOIPs open up a new avenue for perovskite research with their unique structures and functionalities. Melt-quenching is the predominant route to glass formation; however, the absence of a stable liquid state prior to thermal decomposition precludes this method for most HOIPs. In this work, we describe the first mechanochemically-induced crystal-glass transformation of HOIPs as a rapid, green and efficient approach for producing glasses. The amorphous phase was formed from the crystalline phase within 10 minutes of ball-milling, and exhibited glass transition behaviour as evidenced by thermal analysis techniques. Time-resolved
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