ArticleACS applied polymer materials2024
Functionally Gradient Macroporous Polymers: Emulsion Templating Offers Control over Density, Pore Morphology, and Composition.
Article in ACS applied polymer materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Design Strategies and Roles of Hydrogels for Sustainable Energy Conversion and Harvesting from Natural and Biological Environments.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Achieving Lightweight and High Shape Recovery EVA-Based Foams through Supercritical Nitrogen Induced Phase Structure Foaming.ACS omega · 2025Article
- Research on the Resourceful and Efficient Recycling Technology of Waste Thermal Insulation Pipe Material.ACS omega · 2025Article
- A cellulosic fibre foam as a bicycle helmet impact liner for brain injury mitigation in oblique impacts.Heliyon · 2025Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Gradient macroporous polymers were produced by polymerization of emulsion templates comprising a continuous monomer phase and an internal aqueous template phase. To produce macroporous polymers with gradient composition, pore size, and foam density, we varied the template formulation, droplet size, and internal phase ratio of emulsion templates continuously and stacked those prior to polymerization. Using the outlined approach, it is possible to vary one property along the resulting macroporous polymer while retaining the other properties. The elastic moduli and crush strengths change along the gradient of the macroporous polymers; their mechanical properties are dominated by those of the weakest layers in the gradient. Macroporous polymers with gradient chemical composition and thus stiffness provide both high impact load and energy adsorption, rendering the gradient foam suitable for impact protective applications. We show that dual-dispensing and simultaneous blending of two different emulsion formulations in various ratios results in a fine, bidirectional change of the template composition, enabling the production of true gradient macroporous polymers with a high degree of design freedom.
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Registered trials
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