ReviewChemical science2024
A new era of LMCT: leveraging ligand-to-metal charge transfer excited states for photochemical reactions.
Review in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 54 papers.
What it found
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The trial behind it
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Who cites it
54 citing papers in PubMed.
- Heteroleptic CrChemical science · 2026Article
- Carboxylate-Ligand-Based Coordination Polymers and Metal Complexes: From Structural Diversity and Supramolecular Descriptors to Function-Oriented Design.Molecules (Basel, Switzerland) · 2026Review
- Number and Position of Methoxy Substituents Govern Photophysics and Visible-Light Photocatalysis in Earth-Abundant Cu(I) Complexes.ChemSusChem · 2026Article
- Dithiolate auxiliary ligands as electronic modulators in ruthenium-based sensitizers: a DFT and TD-DFT study.RSC advances · 2026Article
- Recent Advances in Porous Hydrogen-Bonded Organic Frameworks for Luminescent and Photoelectric Sensing.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Steric control of copper nuclearity in sulfur ligated oxidase mimics alters catechol and phenoxazinone oxidation.Scientific reports · 2026Article
- Recent efforts of vapour-phase strategies for EUV resist toward high- and hyper-NA extreme ultraviolet lithography.Chemical science · 2026Review
- Overriding the radical polarity matching principle: selective chlorohydroxylation of electron-deficient alkenes enabled by Ce photocatalysis.Chemical science · 2026Article
- Visible-light-driven photocatalytic reduction of Cr(VI) over EDTA-TiOScientific reports · 2026Article
- Tailoring optical nonlinearity and gamma-ray shielding in [Formula: see text]-modified borate-BCZT glasses.Scientific reports · 2026Article
- Photoresponsive Metallo-Supramolecular Systems Constructed From a Bidentate Ligand.Macromolecular rapid communications · 2026Article
- Converting 1,1-Bisborylalkanes into 1,2-Bisborylalkanes Enabled by Iron Ligand-to-Metal Charge Transfer (LMCT) Photocatalysis.Angewandte Chemie (International ed. in English) · 2026Article
- Direct Quantum Yield Measurement of a Ligand-to-Metal Charge Transfer Photocatalyst via Cyclic Voltammetry.Journal of the American Chemical Society · 2026Article
- Synthesis, spectroscopic, characterization, antimicrobial, DNA interaction, DFT and molecular docking studies of a new Cu(II)-Schiff base complex.Scientific reports · 2026Article
- Calcium-molybdenum-cobalt-2-methylimidazole trimetallic organic framework as a saturable absorber for passive mode-locked thulium-holmium doped fiber lasers.Scientific reports · 2026Article
- Functional Metal Complexes for Solar-Light-Driven Energy Conversion.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Controlling Redox and Photophysical Properties of First-Row Transition Metal Complexes via Ligand Perhalogenation.Inorganic chemistry · 2026Article
- Photochemical Aerobic Upcycling of Polystyrene Plastics via Indium Salt-Mediated Synergistic Catalysis.ChemSusChem · 2026Article
- Exploring Hückel Molecular Orbital Energies through Variational and Phase Estimation Quantum Algorithms.The journal of physical chemistry letters · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Ligand-to-metal charge transfer (LMCT) excited states are capable of undergoing a wide array of photochemical reactions, yet receive minimal attention compared to other charge transfer excited states. This work provides general criteria for designing transition metal complexes that exhibit low energy LMCT excited states and routes to drive photochemistry from these excited states. General design principles regarding metal identity, oxidation state, geometry, and ligand sets are summarized. Fundamental photoreactions from these states including visible light-induced homolysis, excited state electron transfer, and other photoinduced chemical transformations are discussed and key design principles for enabling these photochemical reactions are further highlighted. Guided by these fundamentals, this review outlines critical considerations for the future design and application of coordination complexes with LMCT excited states.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.