ArticleChemical science2024
Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Structural and spectroscopic characterization of a Tb(IV) polyoxometalate.Nature communications · 2026Article
- Ligand Design Criteria for the Stability of High Oxidation State Praseodymium Complexes.Inorganic chemistry · 2026Article
- Supramolecular assemblies of tetravalent terbium complex units: syntheses, structure, and materials properties.Chemical science · 2025Article
- Tuning the Electronic Properties of Tetravalent Cerium Complexes via Ligand Derivatization.Inorganic chemistry · 2025Article
- UInorganic chemistry · 2025Article
- Redox and Photochemical Reactivity of Cerium(IV) Carbonate and Carboxylate Complexes Supported by a Tripodal Oxygen Ligand.Inorganic chemistry · 2025Article
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Authors and funding
8 authors.
Funding
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Abstract
Synthetic strategies to isolate molecular complexes of lanthanides, other than cerium, in the +4 oxidation state remain elusive, with only four complexes of Tb(iv) isolated so far. Herein, we present a new approach for the stabilization of Tb(iv) using a siloxide tripodal trianionic ligand, which allows the control of unwanted ligand rearrangements, while tuning the Ln(iii)/Ln(iv) redox-couple. The Ln(iii) complexes, [Ln
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