ArticleChemical science2024
Regulating electron transfer and orbital interaction within metalloporphyrin-MOFs for highly sensitive NO
Er-Xia Chen, Liang He, Mei Qiu, Yongfan Zhang, Yayong Sun, Wen-Hua Li, Jian-Ze Xiao, Jie Chen, Gang Xu, Qipu Lin
Abstract read
In one paragraphArticle in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
2 · The registryThe trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
3 · Its place in the literatureWho cites it
0 citing papers in PubMed.
No citing paper in PubMed yet.
4 · The recordCorrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
5 · Who and what moneyAuthors and funding
10 authors.
Er-Xia ChenState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.
Liang HeState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.ORCID https://orcid.org/0000-0002-4006-993X Mei QiuCollege of Chemistry and Materials, Jiangxi Agricultural University Nanchang Jiangxi 330045 China qium@jxau.edu.cn.
Yayong SunState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.
Wen-Hua LiState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.
Jian-Ze XiaoState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.
Jie ChenState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.
Gang XuState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.ORCID https://orcid.org/0000-0001-8562-0724 Qipu LinState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou Fujian 350002 China gxu@fjirsm.ac.cn linqipu@fjirsm.ac.cn.ORCID https://orcid.org/0000-0002-7723-3676 Funding
No grant is acknowledged in the PubMed record.
6 · The paper itselfAbstract
The understanding of electron transfer pathways and orbital interactions between analytes and adsorption sites in gas-sensitive studies, especially at the atomic level, is currently limited. Herein, we have designed eight isoreticular catechol-metalloporphyrin scaffolds, FeTCP-M and InTCP-M (TCP = 5,10,15,20-tetrakis-catechol-porphyrin, M = Fe, Co, Ni and Zn) with adjustable charge transfer schemes in the coordination microenvironment and precise tuning of orbital interactions between analytes and adsorption sites, which can be used as models for exploring the influence of these factors on gas sensing. Our experimental findings indicate that the sensitivity and selectivity can be modulated using the type of metals in the metal-catechol chains (which regulate the electron transfer routes) and the metalloporphyrin rings (which fine-tune the orbital interactions between analytes and adsorption sites). Among the isostructures, InTCP-Co demonstrates the highest response and selectivity to NO
Identifiers
PMID38725503
PMCPMC11077542
What OpenQuestion holds
Textmetadata
LicenceCC BY-NC
Read underepoch 390