ArticleJournal of the American Chemical Society2024
A Robust Pyrazolate Metal-Organic Framework for Efficient Catalysis of Dehydrogenative C-O Cross Coupling Reaction.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Expansion of the Chemical Space in UiO-Type Metal-Organic Frameworks via the Ugi Four-Component Reaction for Tuned Pore Accessibility.Inorganic chemistry · 2026Article
- Quasi-Closed-Loop Crystal-Amorphous Solid-Wet Gel Transformation in Copper MOFs for Exceptional Cycling Stability in Cascade Reactions.Angewandte Chemie (International ed. in English) · 2026Article
- Two-dimensional Pd-C bonded organometallic framework with dynamic packing transformations.Chemical science · 2026Article
- Structural Exploration of Zirconium Metal-Organic Frameworks Through Linker Desymmetrization and Modulator Compensation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
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Authors and funding
8 authors.
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Abstract
Construction of robust heterogeneous catalysts with atomic precision is a long-sought pursuit in the catalysis field due to its fundamental significance in taming chemical transformations. Herein, we present the synthesis of a single-crystalline pyrazolate metal-organic framework (MOF) named PCN-300, bearing a lamellar structure with two distinct Cu centers and one-dimensional (1D) open channels when stacked. PCN-300 exhibits exceptional stability in aqueous solutions across a broad pH range from 1 to 14. In contrast, its monomeric counterpart assembled through hydrogen bonding displays limited stability, emphasizing the role of Cu-pyrazolate coordination bonds in framework robustness. Remarkably, the synergy of the 1D open channels, excellent stability, and the active Cu-porphyrin sites endows PCN-300 with outstanding catalytic activity in the cross dehydrogenative coupling reaction to form the C-O bond without the "compulsory"
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