ArticleInorganic chemistry2024
Surface-Assisted Selective Air Oxidation of Phosphines Adsorbed on Activated Carbon.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed.
- Article
- TEMPO in Solution, Melted, Solid, and Adsorbed on a Silica Surface: A Paramagnetic NMR Study.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Selective Air Oxidation of Bis- and Trisphosphines Adsorbed on Activated Carbon Surfaces.Molecules (Basel, Switzerland) · 2025Article
- Hydrogen-Bonded Di(hydroperoxy)alkane Adducts of the Type CyMolecules (Basel, Switzerland) · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Trialkyl- and triarylphosphines readily adsorb onto the surface of porous activated carbon (AC) even in the absence of solvents through van der Waals interactions between the lone electron pair and the AC surface. This process has been proven by solid-state NMR techniques. Subsequently, it is demonstrated that the AC enables the fast and selective oxidation of adsorbed phosphines to phosphine oxides at ambient temperature in air. In solution, trialkylphosphines are oxidized to a variety of P(V) species when exposed to the atmosphere, while neat or dissolved triarylphosphines cannot be oxidized with air. When the trialkyl- and triarylphosphines P
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Registered trials
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