Evidence map›Paper›PMID 38721396›Full record

ArticleCatalysis science & technology2024

Activation of alkyl hydroperoxides by manganese complexes of tmtacn for initiation of radical polymerisation of alkenes.

Linda E Eijsink, Andy S Sardjan, Esther G Sinnema, Hugo den Besten, Yanrong Zhang, Ronald Hage, Keimpe J van den Berg, Jitte Flapper, Ben L Feringa, Wesley R Browne

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Catalysis science & technology, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Dependence of OInorganic chemistry · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Linda E EijsinkStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.ORCID https://orcid.org/0000-0002-5426-1025
Andy S SardjanStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.ORCID https://orcid.org/0000-0002-7084-6285
Esther G SinnemaStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.
Hugo den BestenStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.ORCID https://orcid.org/0000-0002-3320-9578
Yanrong ZhangStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.
Ronald HageStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.
Keimpe J van den BergAkzo Nobel Car Refinishes N.V Rijksstraatweg 31 2171 AJ Sassenheim the Netherlands.ORCID https://orcid.org/0000-0002-9980-3289
Jitte FlapperAkzo Nobel Decorative Coatings B.V Rijksstraatweg 31 2171 AJ Sassenheim the Netherlands.
Ben L FeringaStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.ORCID https://orcid.org/0000-0003-0588-8435
Wesley R BrowneStratingh Institute for Chemistry, University of Groningen Nijenborgh 4 9747 AG Groningen the Netherlands w.r.browne@rug.nl.ORCID https://orcid.org/0000-0001-5063-6961

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The activation of alkyl hydroperoxides to generate radicals is a key step in the initiation of radical polymerisations in many industrial applications, not least protective coatings. Cobalt soaps (Co(ii) alkyl carboxylates) are highly effective catalysts under ambient conditions but viable alternatives based on less scarce catalysts are desirable, with especially iron and manganese catalysts showing potential. Manganese complexes of the ligand

Identifiers

PMID38721396
PMCPMC11075131

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.