ArticleNature communications2024
Constructing ordered and tunable extrinsic porosity in covalent organic frameworks via water-mediated soft-template strategy.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- Fundamentals to Prospects: Synthetic Tuning of Covalent Organic Frameworks for Solid-State Hydrogen Storage.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Microenvironment regulation in nanomaterial synthesis.Chemical science · 2026Review
- Weak localized electrons enhance electronic coherence for efficient photocatalytic uranium removal from nuclear wastewater.Nature communications · 2026Article
- Article
- Designing self-adaptative cyclized polyacrylonitrile-polyethyleneimine conjugates enhance uranium extraction from natural seawater.Nature communications · 2025Article
- Flower-Like Covalent Organic Frameworks for Superior Corrosion Resistance and Durability in Epoxy Coatings.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Surfactant-Assisted Construction of Covalent Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Probing Defects in Covalent Organic Frameworks.ACS applied materials & interfaces · 2024Review
Corrections and comments
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Authors and funding
16 authors.
Funding
Abstract
As one of the most attractive methods for the synthesis of ordered hierarchically porous crystalline materials, the soft-template method has not appeared in covalent organic frameworks (COFs) due to the incompatibility of surfactant self-assembly and guided crystallization process of COF precursors in the organic phase. Herein, we connect the soft templates to the COF backbone through ionic bonds, avoiding their crystallization incompatibilities, thus introducing an additional ordered arrangement of soft templates into the anionic microporous COFs. The ion exchange method is used to remove the templates while maintaining the high crystallinity of COFs, resulting in the construction of COFs with ordered hierarchically micropores/mesopores, herein named OHMMCOFs (OHMMCOF-1 and OHMMCOF-2). OHMMCOFs exhibit significantly enhanced functional group accessibility and faster mass transfer rate. The extrinsic porosity can be adjusted by changing the template length, concentration, and ratio. Cationic guanidine-based COFs (OHMMCOF-3) are also constructed using the same method, which verifies the scalability of the soft-template strategy. This work provides a path for constructing ordered and tunable extrinsic porosity in COFs with greatly improved mass transfer efficiency and functional group accessibility.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.