Evidence map›Paper›PMID 38718124›Full record

ArticleScience advances2024

Molecular-caged metal-organic frameworks for energy management.

Minghong Wu, Gengye Lin, Rui Li, Xing Liu, Shumei Liu, Jianqing Zhao, Weiqi Xie

Abstract read
In one paragraph

Article in Science advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Minghong WuSchool of Materials Science and Engineering, Key Laboratory Guangdong High Property and Functional Polymer Materials, Plant Fiber Material Science Research Center, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.ORCID 0000-0001-7918-695X
Gengye LinSchool of Materials Science and Engineering, Key Laboratory Guangdong High Property and Functional Polymer Materials, Plant Fiber Material Science Research Center, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.
Rui LiSchool of Materials Science and Engineering, Key Laboratory Guangdong High Property and Functional Polymer Materials, Plant Fiber Material Science Research Center, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.ORCID 0000-0003-4866-5821
Xing LiuSchool of Materials Science and Engineering, Key Laboratory Guangdong High Property and Functional Polymer Materials, Plant Fiber Material Science Research Center, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.ORCID 0009-0007-4581-7312
Shumei LiuSchool of Materials Science and Engineering, Key Laboratory Guangdong High Property and Functional Polymer Materials, Plant Fiber Material Science Research Center, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.
Jianqing ZhaoSchool of Materials Science and Engineering, Key Laboratory Guangdong High Property and Functional Polymer Materials, Plant Fiber Material Science Research Center, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.ORCID 0000-0001-6942-7430
Weiqi XieSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China.ORCID 0000-0002-7685-3582

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal-organic frameworks (MOFs) hold great promise for diverse applications when combined with polymers. However, a persistent challenge lies in the susceptibility of exposed MOF pores to molecule and polymer penetration, compromising the porosity and overall performance. Here, we design a molecular-caged MOF (MC-MOF) to achieve contracted window without sacrificing the MOF porosity by torsional conjugated ligands. These molecular cages effectively shield against the undesired molecule penetration during polymerization, thereby preserving the pristine porosity of MC-MOF and providing outstanding light and thermal management to the composites. The polymer containing 0.5 wt % MC-MOF achieves an 83% transmittance and an exceptional haze of 93% at 550 nanometers, coupled with remarkable thermal insulation. These MC-MOF/polymer composites offer the potential for more uniform daylighting and reduced energy consumption in sustainable buildings when compared to traditional glass materials. This work delivers a general method to uphold MOF porosity in polymers through molecular cage design, advancing MOF-polymer applications in energy and sustainability.

Identifiers

PMID38718124
PMCPMC11078190

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.