ArticleThe journal of physical chemistry letters2024
Unraveling a Cavity-Induced Molecular Polarization Mechanism from Collective Vibrational Strong Coupling.
Article in The journal of physical chemistry letters, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- A macroscopic condensation theory for vibrational strong coupling effects.Nature communications · 2026Article
- Collectively-Modified Intermolecular Electron Correlations: The Connection of Polaritonic Chemistry and Spin Glass Physics.Chemical reviews · 2026Review
- Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Density-functional tight binding meets Maxwell: unraveling the mysteries of (strong) light-matter coupling efficiently.Nanophotonics (Berlin, Germany) · 2025Article
- Cavity-mediated electron-electron interactions: Renormalizing Dirac states in graphene.Science advances · 2025Article
- Excited State Dynamics of COJournal of the American Chemical Society · 2025Article
- Molecular Polariton Dynamics in Realistic Cavities.Journal of chemical theory and computation · 2025Article
- Modeling Strong Light-Matter Coupling in Correlated Systems: State-Averaged Cavity Quantum Electrodynamics Complete Active Space Self-Consistent Field Theory.Journal of chemical theory and computation · 2025Article
- Theoretical and quantum mechanical deconstruction of vibrational energy transfer pathways modified by collective vibrational strong coupling.Nature communications · 2025Article
- Molecular Polarizability under Vibrational Strong Coupling.Journal of chemical theory and computation · 2025Article
- Quantum-Electrodynamical Density-Functional Theory Exemplified by the Quantum Rabi Model.The journal of physical chemistry. A · 2025Article
- Density-Functional Theory for the Dicke Hamiltonian.Journal of statistical physics · 2025Article
- Disentangling collective coupling in vibrational polaritons with double quantum coherence spectroscopy.The Journal of chemical physics · 2024Article
- Do Molecular Geometries Change Under Vibrational Strong Coupling?The journal of physical chemistry letters · 2024Article
- Extending the Tavis-Cummings model for molecular ensembles-Exploring the effects of dipole self-energies and static dipole moments.The Journal of chemical physics · 2024Article
- Extracting kinetic information from short-time trajectories: relaxation and disorder of lossy cavity polaritons.Nanophotonics (Berlin, Germany) · 2024Article
- A Quantum Chemistry Approach to Linear Vibro-Polaritonic Infrared Spectra with Perturbative Electron-Photon Correlation.The journal of physical chemistry letters · 2024Article
- Machine Learning for Polaritonic Chemistry: Accessing Chemical Kinetics.Journal of the American Chemical Society · 2024Article
- Collective Strong Coupling Modifies Aggregation and Solvation.The journal of physical chemistry letters · 2024Article
- Ab Initio Vibro-Polaritonic Spectra in Strongly Coupled Cavity-Molecule Systems.Journal of chemical theory and computation · 2023Article
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full nonrelativistic Pauli-Fierz problem of an ensemble of strongly coupled molecules in the dilute-gas limit reduces in the cavity Born-Oppenheimer approximation to a cavity-Hartree equation for the electronic structure. Consequently, each individual molecule experiences a self-consistent coupling to the dipoles of all other molecules, which amount to non-negligible values in the thermodynamic limit (large ensembles). Thus, collective vibrational strong coupling can alter individual molecules strongly for localized "hotspots" within the ensemble. Moreover, the discovered cavity-induced polarization pattern possesses a zero net polarization, which resembles a continuous form of a spin glass (or better
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