ArticleJournal of the American Chemical Society2024
Gas-Phase Oxidation of Atmospherically Relevant Unsaturated Hydrocarbons by Acyl Peroxy Radicals.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
3 citing papers in PubMed.
- Gas-Phase Formation of Trioxy Acid via OH-Initiated Aldehyde Oxidation under Atmospheric Conditions.The journal of physical chemistry letters · 2026Article
- A mechanistic understanding of the varying yields of highly oxygenated organic molecules.Nature communications · 2025Article
- Enhanced configurational sampling methods reveal the importance of molecular stiffness for clustering of oxygenated organic molecules.Physical chemistry chemical physics : PCCP · 2025Article
Corrections and comments
- Erratum issued
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This study assesses the atmospheric impact of reactions between unsaturated hydrocarbons such as isoprene and monoterpenes and peroxy radicals containing various functional groups. We find that reactions between alkenes and acyl peroxy radicals have reaction rates high enough to be feasible in the atmosphere and lead to high molar mass accretion products. Moreover, the reaction between unsaturated hydrocarbons and acyl peroxy radicals leads to an alkyl radical, to which molecular oxygen rapidly adds. This finding is confirmed by both theoretical calculations and experiments. The formed perester peroxy radical may either undergo further H-shift reactions or react bimolecularly. The multifunctional oxygenated compounds formed through acyl peroxy radical + alkene reactions are potentially important contributors to particle formation and growth. Thus, acyl peroxy radical-initiated oxidation chemistry may need to be included in atmospheric models.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.