ArticleACS catalysis2023
Deep Electroreductive Chemistry: Harnessing Carbon- and Silicon-based Reactive Intermediates in Organic Synthesis.
Article in ACS catalysis, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Geminal Difunctionalizations of Aliphatic Ketones and Aldehydes Enabled by Thioacetal Activation and Deep Electroreduction.Journal of the American Chemical Society · 2026Article
- Electrolyte-Guided Selectivity Unlocks Pathway Control in Electrochemical Olefin Functionalization.Journal of the American Chemical Society · 2026Article
- Transition-metal-free electrochemical cross-electrophile coupling of activated benzyl alcohols and primary alkyl bromides.Science advances · 2026Article
- Nickelaelectro-Catalyzed Glycosyl-Donor Activation Enabling α-Organic letters · 2025Article
- Deoxygenative Cyanofunctionalization of Aldehydes and Ketones Enabled by Electrochemical Reduction.Journal of the American Chemical Society · 2025Article
- Deoxygenative Functionalization of Alcohols and Carbonyl Compounds via Electrochemical Reduction.Angewandte Chemie (International ed. in English) · 2025Article
- Switchable electrochemical pathways for the selective C(spNature communications · 2025Article
- Markovnikov-Selective Electrocatalytic Hydroalkylation Enabled by Metal-Ligand Cooperative Storage of H-Atom Equivalents.ACS catalysis · 2025Article
- Facile, general allylation of unactivated alkyl halidesChemical science · 2025Article
- The role of silicon in drug discovery: a review.RSC medicinal chemistry · 2024Review
- The merger of electro-reduction and hydrogen bonding activation for a radical Smiles rearrangement.Chemical science · 2024Article
- A guide to troubleshooting metal sacrificial anodes for organic electrosynthesis.Chemical science · 2024Review
- Pulsed electrolysis: enhancing primary benzylic C(spOrganic chemistry frontiers : an international journal of organic chemistry · 2024Article
- Electroreductive Radical Addition-Polar Cyclization Cascade to Access Cycloalkanes.Organic letters · 2024Article
- Transition-metal-catalyst-free electroreductive alkene hydroarylation with aryl halides under visible-light irradiation.Beilstein journal of organic chemistry · 2024Article
- A tutorial on asymmetric electrocatalysis.Chemical Society reviews · 2023Review
- Three-Component Cross-Electrophile Coupling: Regioselective Electrochemical Dialkylation of Alkenes.Journal of the American Chemical Society · 2023Article
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Authors and funding
5 authors.
Funding
Abstract
This Viewpoint outlines our recent contribution in electroreductive synthesis. Specifically, we leveraged deeply reducing potentials provided by electrochemistry to generate radical and anionic intermediates from readily available alkyl halides and chlorosilanes. Harnessing the distinct reactivities of radicals and anions, we have achieved several challenging transformations to construct C-C, C-Si, and Si-Si bonds. We highlight the mechanistic design principle that underpinned the development of each transformation and provide a view forward on future opportunities in growing area of reductive electrosynthesis.
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