ArticleNature materials2024
Electrochemomechanical failure in layered oxide cathodes caused by rotational stacking faults.
Article in Nature materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
17 citing papers in PubMed.
- Interfacial Failure Cascade and Modulation Strategies for Layered Oxide Cathodes in Sodium-Ion Batteries.Molecules (Basel, Switzerland) · 2026Review
- Mn vacancies in MnChemical science · 2026Article
- Tailoring Local Superstructure Units to Mitigate Voltage Decay in Na-Ion Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Fast formation to reinforce lithium-rich cathodes.Nature · 2026Article
- Revisiting Deep Delithiation of LiNiSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Layered oxide cathodes for sodium-ion batteries: origins of microcracks and countermeasures.Chemical science · 2026Review
- High-energy anode-free Li metal batteries with in-built surface-fluorinated Li-rich Mn-based cathodes.Science advances · 2026Article
- Understanding the degradation complexity of ultrahigh-energy lithium metal batteries.Nature reviews. Chemistry · 2026Review
- Decoding High-voltage LiCoOAdvanced materials (Deerfield Beach, Fla.) · 2026Review
- Low-Temperature Defect Healing in the Layered Zintl Phase LiInorganic chemistry · 2026Article
- Impact of the dChemical science · 2026Article
- Toward Practical Li-Ion Cells With Li/Mn-Rich Layered Oxide Cathodes: A Techno-Economic Perspective on Material and Cell Design.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Facile Synthesis of Nanolayered Manganese Oxide for the Efficient and Selective Removal of Strontium(II) from Nuclear Wastewater.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Degradation Mechanism Induced by Depth-Dependent Inhomogeneity in Thick High-Areal-Capacity Graphite Electrode.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dynamic doping and interphase stabilization for cobalt-free and high-voltage Lithium metal batteries.Nature communications · 2025Article
- Enabling the synthesis of O3-type sodium anion-redox cathodes via atmosphere modulation.Nature communications · 2025Article
- Unravelling complex mechanisms in materials processes with cryogenic electron microscopy.Chemical science · 2025Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
8 authors.
Funding
Abstract
Electrochemomechanical degradation is one of the most common causes of capacity deterioration in high-energy-density cathodes, particularly intercalation-based layered oxides. Here we reveal the presence of rotational stacking faults (RSFs) in layered lithium transition-metal oxides, arising from specific stacking sequences at different angles, and demonstrate their critical role in determining structural/electrochemical stability. Our combined experiments and calculations show that RSFs facilitate oxygen dimerization and transition-metal migration in layered oxides, fostering microcrack nucleation/propagation concurrently with cumulative electrochemomechanical degradation on cycling. We further show that thermal defect annihilation as a potential solution can suppress RSFs, reducing microcracks and enhancing cyclability in lithium-rich layered cathodes. The common but previously overlooked occurrence of RSFs suggests a new synthesis guideline of high-energy-density layered oxide cathodes.
Identifiers
38702413What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.