ArticleJournal of the American Chemical Society2024
Mild-Temperature Supercritical Water Confined in Hydrophobic Metal-Organic Frameworks.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Nanoconfinement drives water ordering.National science review · 2026Article
- When 20% Is Enough: Counterintuitive Contact Angle Maxima on Chemically Heterogeneous Hydrophobic/Hydrophilic Surfaces.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Article
- Topology-Independent Water Extrusion from Hydrophobic Nanopores above 200 °C.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Water Adsorption in Metal-Organic Frameworks: Characteristics, Mechanisms, and Structure-Property Relationships.Journal of the American Chemical Society · 2025Article
- Crystallite Size Effects on the Heat of Water Intrusion/Extrusion into/from Metal-Organic Frameworks.The journal of physical chemistry letters · 2025Article
Corrections and comments
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Authors and funding
16 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Fluids under extreme confinement show characteristics significantly different from those of their bulk counterpart. This work focuses on water confined within the complex cavities of highly hydrophobic metal-organic frameworks (MOFs) at high pressures. A combination of high-pressure intrusion-extrusion experiments with molecular dynamic simulations and synchrotron data reveals that supercritical transition for MOF-confined water takes place at a much lower temperature than in bulk water, ∼250 K below the reference values. This large shifting of the critical temperature (
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Registered trials
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