ArticleChemical science2024
Programmable synthesis of organic cages with reduced symmetry.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Towards next generation enzyme mimics through local electric field control in organic cage catalysts.Chemical science · 2026Article
- Unbiased Structure Prediction of Sophisticated Cage Structures.Angewandte Chemie (International ed. in English) · 2026Article
- Reduced Symmetry Metal-Organic Cage-to-Framework Materials.Angewandte Chemie (International ed. in English) · 2026Article
- White-light powered autonomous molecular ratchet drives PdChemical science · 2026Article
- Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa-Cationic Organic Cages.Angewandte Chemie (International ed. in English) · 2025Article
- Chirality-Assisted Self-Assembly of Low-Symmetry Noncovalent Capsules with Quantitative Diastereoisomeric Selection.Journal of the American Chemical Society · 2025Article
- Formation of a PdJACS Au · 2025Article
- Spherical Amides withMolecules (Basel, Switzerland) · 2025Article
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- Enzyme-like Acyl Transfer Catalysis in a Bifunctional Organic Cage.Journal of the American Chemical Society · 2024Article
- Exploration of the polymorphic solid-state landscape of an amide-linked organic cage using computation and automation.Chemical communications (Cambridge, England) · 2024Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Integrating symmetry-reducing methods into self-assembly methodology is desirable to efficiently realise the full potential of molecular cages as hosts and catalysts. Although techniques have been explored for metal organic (coordination) cages, rational strategies to develop low symmetry organic cages remain limited. In this article, we describe rules to program the shape and symmetry of organic cage cavities by designing edge pieces that bias the orientation of the amide linkages. We apply the rules to synthesise cages with well-defined cavities, supported by evidence from crystallography, spectroscopy and modelling. Access to low-symmetry, self-assembled organic cages such as those presented, will widen the current bottleneck preventing study of organic enzyme mimics, and provide synthetic tools for novel functional material design.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.