ArticleJournal of the American Chemical Society2024
Steric Control of Luminescence in Phenyl-Substituted Trityl Radicals.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed, 39 citations in OpenAlex.
- Water-Soluble Luminescent Trityl Radical for Fluorescence/Magnetic Resonance Dual-Modal Imaging Probe.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- 1,4-Dihydropyrrolo[3,2-Organic chemistry frontiers : an international journal of organic chemistry · 2026Article
- Spin characteristics of organic radicals from a single-molecule junction perspective.Chemical science · 2026Review
- Molecular Diradical Spin Qubits in a Crystalline Host as a Platform for Quantum Sensing.ACS central science · 2026Article
- Photoinduced radical emission from flexible organic crystals.Light, science & applications · 2026Article
- Simple Substitutions into Donor-Acceptor Radicals to Construct Highly Luminescent Radicals and Solvent-Responsive Ionic Radical Polymers.Molecules (Basel, Switzerland) · 2026Article
- Intrinsic intermolecular photoinduced charge separation in organic radical semiconductors.Nature materials · 2026Article
- Oxidation-Active Radical TTM-DMODPA for Catalysis-Free Hydrogen Peroxide Colorimetric Sensing.Biosensors · 2025Article
- Luminescence Efficiency Enhanced by Simple Substitutions on Donor and Acceptor in Radicals with Donor-Acceptor Structure.Molecules (Basel, Switzerland) · 2025Article
- On the photoluminescence in triarylmethyl-centered mono-, di-, and multiradicals.Beilstein journal of organic chemistry · 2025Review
Corrections and comments
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Authors and funding
13 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Triphenylmethyl (trityl) radicals have shown potential for use in organic optoelectronic applications, but the design of practical trityl structures has been limited to donor/radical charge-transfer systems due to the poor luminescence of alternant symmetry hydrocarbons. Here, we circumvent the symmetry-forbidden transition of alternant hydrocarbons via excited-state symmetry breaking in a series of phenyl-substituted tris(2,4,6-trichlorophenyl)methyl (TTM) radicals. We show that 3-fold phenyl substitution enhances the emission of the TTM radical and that steric control modulates the optical properties in these systems. Simple
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.