Evidence map›Paper›PMID 38693110›Full record

ArticleNature communications2024

The role of charge in microdroplet redox chemistry.

Joseph P Heindel, R Allen LaCour, Teresa Head-Gordon

Erratum issuedAbstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 31 papers.

0numbers the graph read from it
0cells of the map it votes in
31citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

31 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Accelerated Chemistry in Microdroplets.Accounts of chemical research · 2026
    Article
  6. Article
  7. Article
  8. The Intricate Nonadiabatic Dynamics of NOJournal of the American Chemical Society · 2026
    Article
  9. Early-stage drug discovery in a new-generation ultrahigh-throughput mass spectrometry platform.Proceedings of the National Academy of Sciences of the United States of America · 2026
    Article
  10. Article
  11. Origins of the Intrinsic Redox Activity of Biomolecular Condensates.Journal of the American Chemical Society · 2026
    Article
  12. Review
  13. Article
  14. Recent Advances in Reactive Microdroplets for Clean Water and Energy.Advanced materials (Deerfield Beach, Fla.) · 2025
    Review
  15. Article
  16. Article
  17. Oil-water interfaces drive gold precipitation via microdroplet chemistry in thermal geological systems.Proceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  18. Review
  19. Article
  20. Article
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

3 authors.

Joseph P HeindelKenneth S. Pitzer Theory Center and Department of Chemistry, Berkeley, CA, USA.
R Allen LaCourKenneth S. Pitzer Theory Center and Department of Chemistry, Berkeley, CA, USA.
Teresa Head-GordonKenneth S. Pitzer Theory Center and Department of Chemistry, Berkeley, CA, USA. thg@berkeley.edu.ORCID http://orcid.org/0000-0003-0025-8987

Funding

National Science Foundation (NSF) CHE-2313791United States Department of Defense | United States Air Force | AFMC | Air Force Office of Scientific Research (AF Office of Scientific Research) FA9550-21-1-0170
6 · The paper itself

Abstract

In charged water microdroplets, which occur in nature or in the lab upon ultrasonication or in electrospray processes, the thermodynamics for reactive chemistry can be dramatically altered relative to the bulk phase. Here, we provide a theoretical basis for the observation of accelerated chemistry by simulating water droplets of increasing charge imbalance to create redox agents such as hydroxyl and hydrogen radicals and solvated electrons. We compute the hydration enthalpy of OH

Identifiers

PMID38693110
PMCPMC11519639

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.