ArticleDalton transactions (Cambridge, England : 2003)2024
The coordination of alkali-metal nickelates to organic π-systems: synthetic, structural and spectroscopic insights.
Article in Dalton transactions (Cambridge, England : 2003), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Highly Selective Synthesis ofACS omega · 2025Article
- Straightforward Superbase-Mediated Reductive O-Phosphorylation of Aromatic and Heteroaromatic Ketones with Red Phosphorus in the Superbase Suspension KOH/DMSO(HMolecules (Basel, Switzerland) · 2025Article
- Mechanistic insights on C(acyl)-N functionalisation mediated by late transition metals.Dalton transactions (Cambridge, England : 2003) · 2024Review
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3 authors.
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Abstract
Low-valent nickelates have recently been shown to be key intermediates in challenging cross-coupling reactions using aryl ethers as electrophiles. Key for the success of these transformations is the activation of the substrate through π-coordination to the nickelate intermediate, however there is still limited knowledge about the fundamental structure and coordination chemistry of these heterobimetallic complexes. Herein, we report the synthesis, structures, and spectroscopic analysis of a diverse family of alkali-metal nickelates derived from phenyl-alkali-metal reagents and Ni(
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