Evidence map›Paper›PMID 38678049›Full record

ArticleNature communications2024

Visible-light-excited robust room-temperature phosphorescence of dimeric single-component luminophores in the amorphous state.

Danman Guo, Wen Wang, Kaimin Zhang, Jinzheng Chen, Yuyuan Wang, Tianyi Wang, Wangmeng Hou, Zhen Zhang, Huahua Huang, Zhenguo Chi and 1 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
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  4. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Danman GuoPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China.
Wen WangPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China.
Kaimin ZhangPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China.
Jinzheng ChenPCFM Lab, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, P. R. China.
Yuyuan WangPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China.
Tianyi WangPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China.
Wangmeng HouPCFM Lab, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, P. R. China.ORCID http://orcid.org/0000-0003-0637-7223
Zhen ZhangPCFM Lab, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, P. R. China.ORCID http://orcid.org/0000-0001-5760-7055
Huahua HuangPCFM Lab, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, P. R. China.ORCID http://orcid.org/0000-0003-0377-5015
Zhenguo ChiPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China.ORCID http://orcid.org/0000-0001-9772-5363
Zhiyong YangPCFM Lab, Guangdong Engineering Technology Research Center for High-performance Organic and Polymer Photoelectric Functional Films, GBRCE for Functuional Molecular Engineering, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, P. R. China. yangzhy29@mail.sysu.edu.cn.ORCID http://orcid.org/0000-0003-1670-9981

Funding

Natural Science Foundation of Guangdong Province (Guangdong Natural Science Foundation) 2023A1515012679
6 · The paper itself

Abstract

Organic room temperature phosphorescence (RTP) has significant potential in various applications of information storage, anti-counterfeiting, and bio-imaging. However, achieving robust organic RTP emission of the single-component system is challenging to overcome the restriction of the crystalline state or other rigid environments with cautious treatment. Herein, we report a single-component system with robust persistent RTP emission in various aggregated forms, such as crystal, fine powder, and even amorphous states. Our experimental data reveal that the vigorous RTP emissions rely on their tight dimers based on strong and large-overlap π-π interactions between polycyclic aromatic hydrocarbon (PAH) groups. The dimer structure can offer not only excitons in low energy levels for visible-light excited red long-lived RTP but also suppression of the nonradiative decays even in an amorphous state for good resistance of RTP to heat (up to 70 °C) or water. Furthermore, we demonstrate the water-dispersible nanoparticle with persistent RTP over 600 nm and a lifetime of 0.22 s for visible-light excited cellular and in-vivo imaging, prepared through the common microemulsion approach without overcaution for nanocrystal formation.

Identifiers

PMID38678049
PMCPMC11055858

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.