Photoinduced Site-Selective Aryl C-H Borylation with Electron-Donor-Acceptor Complex Derived from B

Manhong Li, Yi-Hui Deng, Qianqian Chang, Jinyuan Li, Chao Wang, Leifeng Wang, Tian-Yu Sun

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

7 authors.

Manhong LiKey Lab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen 518055, China.

Yi-Hui DengKey Lab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen 518055, China.

Qianqian ChangSchool of Pharmaceutical Sciences (Shenzhen), Sun Yat-sen University, No. 66, Gongchang Road, Shenzhen 518107, China.ORCID 0000-0003-1056-7556

Jinyuan LiShanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Chao WangKey Lab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen 518055, China.

Leifeng WangSchool of Pharmaceutical Sciences (Shenzhen), Sun Yat-sen University, No. 66, Gongchang Road, Shenzhen 518107, China.

Tian-Yu SunKey Lab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen 518055, China.ORCID 0000-0002-7746-479X

Funding

Shenzhen Science and Technology Program RCBS20210706092258097the Fundamental Research Funds for the Central Universities 23ykbj010the Guangdong Basic and Applied Basic Research Foundation 2022A1515011994the National Natural Science Foundation of China 21933004the National Natural Science Foundation of China 22271316the Sun Yat-sen University Startup Fund startup fundthe Technology & Innovation Commission of Shenzhen Municipality SZBH202103

6 · The paper itself

Abstract

Due to boron's metalloid properties, aromatic boron reagents are prevalent synthetic intermediates. The direct borylation of aryl C-H bonds for producing aromatic boron compounds offers an appealing, one-step solution. Despite significant advances in this field, achieving regioselective aryl C-H bond borylation using simple and readily available starting materials still remains a challenge. In this work, we attempted to enhance the reactivity of the electron-donor-acceptor (EDA) complex by selecting different bases to replace the organic base (NEt

Indexed as

B2Pin2borylationC-H bondelectron-donor-acceptorisoquinolinephotocatalysis

Identifiers

PMID38675603

DOI10.3390/molecules29081783

PMCPMC11052414

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