Doping Ferrocene-Based Conjugated Microporous Polymers with 7,7,8,8-Tetracyanoquinodimethane for Efficient Photocatalytic CO

Shenglin Wang, Qianqian Yan, Hui Hu, Xiaofang Su, Huanjun Xu, Jianyi Wang, Yanan Gao

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Shenglin WangKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No 58, Renmin Avenue, Haikou 570228, China.

Qianqian YanKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No 58, Renmin Avenue, Haikou 570228, China.

Hui HuKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No 58, Renmin Avenue, Haikou 570228, China.

Xiaofang SuKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No 58, Renmin Avenue, Haikou 570228, China.

Huanjun XuSchool of Science, Qiongtai Normal University, Haikou 571127, China.

Jianyi WangKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No 58, Renmin Avenue, Haikou 570228, China.ORCID 0009-0002-6006-7592

Yanan GaoKey Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan University, No 58, Renmin Avenue, Haikou 570228, China.ORCID 0000-0002-5543-6296

Funding

Key Research and Development Project of Hainan Province ZDYF2024GXJS005Major Science and Technology Plan of Hainan Province ZDKJ202016National Natural Science Foundation of China 22105053National Natural Science Foundation of China 22165009Natural Science Foundation of Hainan Province 521QN209

6 · The paper itself

Abstract

The design and synthesis of organic photocatalysts remain a great challenge due to their strict structural constraints. However, this could be mitigated by achieving structural flexibility by constructing permanent porosity into the materials. Conjugated microporous polymers (CMPs) are an emerging class of porous materials with an amorphous, three-dimensional network structure, which makes it possible to integrate the elaborate functional groups to enhance photocatalytic performance. Here, we report the synthesis of a novel CMP, named TAPFc-TFPPy-CMP, constructed by 1,1'3,3'-tetra(4-aminophenyl)ferrocene (TAPFc) and 1,3,6,8-tetrakis(4-formylphenyl)pyrene (TFPPy) monomers. The integration of the

Indexed as

conjugated microporous polymerdopingferrocenephotocatalytic CO2 reductionTCNQ

Identifiers

PMID38675557

DOI10.3390/molecules29081738

PMCPMC11052251

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