Evidence map›Paper›PMID 38675045›Full record

ArticlePolymers2024

Searching for the Achilles' Heel of Urethane Linkage-An Energetic Perspective.

Tamás Horváth, Karina Kecskés, Anikó Jordán Csábrádiné, Emma Szőri-Dorogházi, Béla Viskolcz, Milán Szőri

Abstract read
In one paragraph

Article in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Tamás HorváthInstitute of Chemistry, University of Miskolc, Miskolc-Egyetemváros A/2, H-3515 Miskolc, Hungary.
Karina KecskésInstitute of Chemistry, University of Miskolc, Miskolc-Egyetemváros A/2, H-3515 Miskolc, Hungary.
Anikó Jordán CsábrádinéInstitute of Chemistry, University of Miskolc, Miskolc-Egyetemváros A/2, H-3515 Miskolc, Hungary.ORCID 0009-0000-4213-8823
Emma Szőri-DorogháziInstitute of Chemistry, University of Miskolc, Miskolc-Egyetemváros A/2, H-3515 Miskolc, Hungary.
Béla ViskolczHigher Education and Industrial Cooperation Centre, University of Miskolc, H-3515 Miskolc, Hungary.ORCID 0000-0002-0777-9569
Milán SzőriInstitute of Chemistry, University of Miskolc, Miskolc-Egyetemváros A/2, H-3515 Miskolc, Hungary.ORCID 0000-0003-4895-0999

Funding

European Regional Development Fund (Hungary) GINOP-2.3.4-15-2016-00004National Research, Development and Innovation Fund (Hungary) TKP2021-NVA-14New National Excellence Program of the Ministry for Culture and Innovation (Hungary) ÚNKP-23-2
6 · The paper itself

Abstract

A sudden increase in polyurethane (PU) production necessitates viable recycling methods for the waste generated. PU is one of the most important plastic materials with a wide range of applications; however, the stability of the urethane linkage is a major issue in chemical recycling. In this work, termination reactions of a model urethane molecule, namely methyl N-phenyl carbamate (MPCate), are investigated using G3MP2B3 composite quantum chemical method. Our main goal was to gain insights into the energetic profile of urethane bond termination and find an applicable chemical recycling method. Hydrogenation, hydrolysis, methanolysis, peroxidation, glycolysis, ammonolysis, reduction with methylamine and termination by dimethyl phosphite were explored in both gas and condensed phases. Out of these chemicals, degradation by H

Indexed as

ammonolysisglycolysishydrogenationhydrolysismethanolysisperoxidationurethane bond

Identifiers

PMID38675045
PMCPMC11053941

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.