ArticleJournal of the American Chemical Society2024
Intermolecular Proton-Coupled Electron Transfer Reactivity from a Persistent Charge-Transfer State for Reductive Photoelectrocatalysis.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
9 citing papers in PubMed, 30 citations in OpenAlex.
- Proton-gated multisite concerted proton-electron transfer-like pathway in a dual-atom framework for selective water purification.Nature communications · 2026Article
- Driving Forces and Spin-Gated Reactivity of N5-Hydropyrimidopteridinetetraone Radicals in Photocatalysis.The Journal of organic chemistry · 2026Article
- Unraveling Defect-Dependent Conductivity-Type Switching in CuFeACS applied materials & interfaces · 2026Article
- Recent Advances in Mediator and Proton Relay Usage in Molecular Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Mechanistic Studies of the Proton-Coupled Electron Transfer Reactivity of a Cobalt Complex with a Proton-Responsive PNP Pincer-Type Ligand.Inorganic chemistry · 2025Article
- On the mechanism of photodriven hydrogenations of NProceedings of the National Academy of Sciences of the United States of America · 2025Article
- Iridium Polypyridyl Carboxylates as Excited-State PCET Catalysts for the Functionalization of Unactivated C-H Bonds.Journal of the American Chemical Society · 2025Article
- Enhanced Photocatalytic Proton-Coupled Electron Transfer by Ligand Design in a Zr Coordination Cage.ChemSusChem · 2025Article
- Reductive Photocatalytic Proton-Coupled Electron Transfer by a Zirconium-Based Molecular Platform.Angewandte Chemie (International ed. in English) · 2024Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Interest in applying proton-coupled electron transfer (PCET) reagents in reductive electro- and photocatalysis requires strategies that mitigate the competing hydrogen evolution reaction. Photoexcitation of a PCET donor to a charge-separated state (CSS) can produce a powerful H-atom donor capable of being electrochemically recycled at a comparatively anodic potential corresponding to its ground state. However, the challenge is designing a mediator with a sufficiently long-lived excited state for bimolecular reactivity. Here, we describe a powerful ferrocene-derived photoelectrochemical PCET mediator exhibiting an unusually long-lived CSS (τ ∼ 0.9 μs). In addition to detailed photophysical studies, proof-of-concept stoichiometric and catalytic proton-coupled reductive transformations are presented, which illustrate the promise of this approach.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.