ArticleJournal of the American Chemical Society2024
Metal-Solvent Complex Formation at the Surface of InP Colloidal Quantum Dots.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed.
- Reaction-Driven Self-Organization of Nanocrystals by Kinetic Control of Inhomogeneous Photopolymerization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Colloidal InSb Quantum Dots for eSWIR Photodetection via Decoupling Nucleation and Growth.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Steric Effect-Controlled Atomic Passivation of Colloidal InAs Quantum Dots for Infrared Photodetectors.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Surface Passivation and Luminescence Mechanisms in InP Quantum Dots Toward High-Efficiency and Stable QLED Emission.Luminescence : the journal of biological and chemical luminescence · 2026Review
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The surface chemistry of colloidal semiconductor nanocrystals (QDs) profoundly influences their physical and chemical attributes. The insulating organic shell ensuring colloidal stability impedes charge transfer, thus limiting optoelectronic applications. Exchanging these ligands with shorter inorganic ones enhances charge mobility and stability, which is pivotal for using these materials as active layers for LEDs, photodetectors, and transistors. Among those, InP QDs also serve as a model for surface chemistry investigations. This study focuses on group III metal salts as inorganic ligands for InP QDs. We explored the ligand exchange mechanism when metal halide, nitrate, and perchlorate salts of group III (Al, In Ga), common Lewis acids, are used as ligands for the conductive inks. Moreover, we compared the exchange mechanism for two starting model systems: InP QDs capped with myristate and oleylamine as X- and L-type native organic ligands, respectively. We found that all metal halide, nitrate, and perchlorate salts dissolved in polar solvents (such as
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Registered trials
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