Evidence map›Paper›PMID 38668170›Full record

ArticleNanomaterials (Basel, Switzerland)2024

Evaluation of the Thermal, Chemical, Mechanical, and Microbial Stability of New Nanohybrids Based on Carboxymethyl-Scleroglucan and Silica Nanoparticles for EOR Applications.

Rubén H Castro, Laura M Corredor, Sebastián Llanos, Zully P Rodríguez, Isidro Burgos, Jhorman A Niño, Eduardo A Idrobo, Arnold R Romero Bohórquez, Karol Zapata Acosta, Camilo A Franco and 1 more

Abstract read
In one paragraph

Article in Nanomaterials (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Rubén H CastroGrupo de Investigación en Fenómenos de Superficie-Michael Polanyi, Facultad de Minas, Universidad Nacional de Colombia-Sede Medellín, Medellín 050034, Colombia.
Laura M CorredorCentro de Innovación y Tecnología-ICP, Ecopetrol S.A., Piedecuesta 681011, Colombia.
Sebastián LlanosGrupo de Investigación en Química Estructural (GIQUE), Escuela de Química, Universidad Industrial de Santander, Bucaramanga 680002, Colombia.ORCID 0000-0002-4774-7043
Zully P RodríguezPSL Proanálisis, Piedecuesta 680005, Colombia.
Isidro BurgosGrupo de Investigación en Química Estructural (GIQUE), Escuela de Química, Universidad Industrial de Santander, Bucaramanga 680002, Colombia.
Jhorman A NiñoCentro de Innovación y Tecnología-ICP, Ecopetrol S.A., Piedecuesta 681011, Colombia.
Eduardo A IdroboCentro de Innovación y Tecnología-ICP, Ecopetrol S.A., Piedecuesta 681011, Colombia.
Arnold R Romero BohórquezGrupo de Investigación en Química Estructural (GIQUE), Escuela de Química, Universidad Industrial de Santander, Bucaramanga 680002, Colombia.ORCID 0000-0003-3479-3865
Karol Zapata AcostaGrupo de Investigación en Fenómenos de Superficie-Michael Polanyi, Facultad de Minas, Universidad Nacional de Colombia-Sede Medellín, Medellín 050034, Colombia.ORCID 0000-0003-0850-4556
Camilo A FrancoGrupo de Investigación en Fenómenos de Superficie-Michael Polanyi, Facultad de Minas, Universidad Nacional de Colombia-Sede Medellín, Medellín 050034, Colombia.ORCID 0000-0002-6886-8338
Farid B CortésGrupo de Investigación en Fenómenos de Superficie-Michael Polanyi, Facultad de Minas, Universidad Nacional de Colombia-Sede Medellín, Medellín 050034, Colombia.ORCID 0000-0003-1207-3859

Funding

MinCiencias Agreement FP44842-326-2017 (D.Nal Empresa 758 of 2016
6 · The paper itself

Abstract

Scleroglucan (SG) is resistant to harsh reservoir conditions such as high temperature, high shear stresses, and the presence of chemical substances. However, it is susceptible to biological degradation because bacteria use SG as a source of energy and carbon. All degradation effects lead to viscosity loss of the SG solutions, affecting their performance as an enhanced oil recovery (EOR) polymer. Recent studies have shown that nanoparticles (NPs) can mitigate these degradative effects. For this reason, the EOR performance of two new nanohybrids (NH-A and NH-B) based on carboxymethyl-scleroglucan and amino-functionalized silica nanoparticles was studied. The susceptibility of these products to chemical, mechanical, and thermal degradation was evaluated following standard procedures (API RP 63), and the microbial degradation was assessed under reservoir-relevant conditions (1311 ppm and 100 °C) using a bottle test system. The results showed that the chemical reactions for the nanohybrids obtained modified the SG triple helix configuration, impacting its viscosifying power. However, the nanohybrid solutions retained their viscosity during thermal, mechanical, and chemical degradation experiments due to the formation of a tridimensional network between the nanoparticles (NPs) and the SG. Also, NH-A and NH-B solutions exhibited bacterial control because of steric hindrances caused by nanoparticle modifications to SG. This prevents extracellular glucanases from recognizing the site of catalysis, limiting free glucose availability and generating cell death due to substrate depletion. This study provides insights into the performance of these nanohybrids and promotes their application in reservoirs with harsh conditions.

Indexed as

biodegradationcarboxymethyl-scleroglucanEORnanohybridscleroglucan

Identifiers

PMID38668170
PMCPMC11055106

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LicenceCC BY
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.