Isolation and Reactivity of Arylnickel(II) Complexes in Nickel-Catalyzed Borylation of Aryl Fluorosulfates.

Manoj Kumar Sahoo, Jeong Woo Lee, Soochan Lee, Wonyoung Choe, Byunghyuck Jung, Jaesung Kwak, Sung You Hong

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Article in JACS Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Manoj Kumar SahooDepartment of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.

Jeong Woo LeeDepartment of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.

Soochan LeeDepartment of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.

Wonyoung ChoeDepartment of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.ORCID https://orcid.org/0000-0003-0957-1187

Byunghyuck JungDepartment of Physics and Chemistry, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 42988, Republic of Korea.ORCID https://orcid.org/0000-0002-8582-082X

Jaesung KwakInfectious Diseases Therapeutic Research Center, Korea Research Institute of Chemical Technology (KRICT), Division of Medicinal Chemistry and Pharmacology, KRICT School, University of Science and Technology (UST), Daejeon 34114, Republic of Korea.ORCID https://orcid.org/0000-0001-8010-7307

Sung You HongDepartment of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea.ORCID https://orcid.org/0000-0002-5785-4475

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Aryl fluorosulfates have emerged as versatile SuFExable substrates, harnessing the reactivity of the S-F bond. In this study, we unveil their alternative synthetic utility in nickel-catalyzed borylation via C-O bond activation. This method highlights mild reaction conditions, a broad substrate scope, and moderate functional group tolerance, rendering it a practical and appealing approach for synthesizing a diverse array of aryl boronate esters. Furthermore, computational analysis sheds light on the reaction pathways, uncovering the participation of LNi(0) and LNi(II)ArX species. This insight is supported by the

Identifiers

PMID38665649

DOI10.1021/jacsau.4c00128

PMCPMC11040702

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