Competing Mechanisms in Palladium-Catalyzed Alkoxycarbonylation of Styrene.

Jaya Mehara, Mariarosa Anania, Pavel Kočovský, Jana Roithová

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Article in ACS catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

3.7field-weighted citation impact, top 6% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 15 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 2 countries.

Jaya MeharaDepartment of Spectroscopy and Catalysis, Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands.

Mariarosa AnaniaDepartment of Spectroscopy and Catalysis, Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands.

Pavel KočovskýDepartment of Organic Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, Prague 2 12843, Czech Republic.

Jana RoithováDepartment of Spectroscopy and Catalysis, Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, Nijmegen 6525 AJ, The Netherlands.

Radboud University Nijmegen · NLCzech Academy of Sciences, Institute of Organic Chemistry and Biochemistry · CZ

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Palladium-catalyzed carbonylation is a versatile method for the synthesis of various aldehydes, esters, lactones, or lactams. Alkoxycarbonylation of alkenes with carbon monoxide and alcohol produces either saturated or unsaturated esters as a result of two distinct catalytic cycles. The existing literature presents an inconsistent account of the procedures favoring oxidative carbonylation products. In this study, we have monitored the intermediates featured in both catalytic cycles of the methoxycarbonylation of styrene PhCH=CH

Identifiers

PMID38660606

DOI10.1021/acscatal.4c00966

PMCPMC11036401

OpenAlexW4393375769

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LicenceCC BY

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.