Evidence map›Paper›PMID 38659662›Full record

ArticleCrystal growth & design2024

Supramolecular Mille-Feuille: Adaptive Guest Inclusion in a New Aliphatic Guanidinium Monosulfonate Hydrogen-Bonded Framework.

Alexandra M Dillon, Anna Yusov, Mohammad T Chaudhry, Justin A Newman, Krystyna M Demkiw, K A Woerpel, Alfred Y Lee, Michael D Ward

Abstract read
In one paragraph

Article in Crystal growth & design, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Hydrogen-bonded frameworks for conformational analysis of reactive substrates.Chemical communications (Cambridge, England) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Alexandra M DillonDepartment of Chemistry, New York University, New York, New York 10003, United States.ORCID https://orcid.org/0000-0003-4680-0284
Anna YusovDepartment of Chemistry, New York University, New York, New York 10003, United States.ORCID https://orcid.org/0000-0002-6880-0421
Mohammad T ChaudhryAnalytical Research and Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.ORCID https://orcid.org/0000-0002-1482-388X
Justin A NewmanAnalytical Research and Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.ORCID https://orcid.org/0000-0002-2498-1259
Krystyna M DemkiwDepartment of Chemistry, New York University, New York, New York 10003, United States.ORCID https://orcid.org/0000-0001-5457-3291
K A WoerpelDepartment of Chemistry, New York University, New York, New York 10003, United States.
Alfred Y LeeAnalytical Research and Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.ORCID https://orcid.org/0000-0003-3684-4101
Michael D WardDepartment of Chemistry, New York University, New York, New York 10003, United States.ORCID https://orcid.org/0000-0002-2090-781X

Funding

Stereoselective Reactions of Oxocarbenium Ions and Related IntermediatesR35GM148203 · NIGMS · NEW YORK UNIVERSITY · PI KEITH ALLEN WOERPEL · 2023 to 2026
$1.9M
NIGMS NIH HHS R35 GM148203
6 · The paper itself

Abstract

During the past three decades, the ability of guanidinium arenesulfonate host frameworks to encapsulate a wide range of guests has been amply demonstrated, with more than 700 inclusion compounds realized. Herein, we report crystalline inclusion compounds based on a new aliphatic host, guanidinium cyclohexanemonosulfonate, which surprisingly exhibits four heretofore unobserved architectures, as described by the projection topologies of the organosulfonate residues above and below hydrogen-bonded guanidinium sulfonate sheets. The inclusion compounds adopt a layer motif of guanidinium sulfonate sheets interleaved with guest molecules, resembling a mille-feuille pastry. The aliphatic character of this remarkably simple host, combined with access to greater architectural diversity and adaptability, enables the host framework to accommodate a wide range of guests and promises to expand the utility of guanidinium organosulfonate hosts.

Identifiers

PMID38659662
PMCPMC11036357

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.