ArticleInorganic chemistry2024
(P^N^C) Ligands to Stabilize Gold(III): A Straightforward Access to Hydroxo, Formate, and Hydride Complexes.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed, 8 citations in OpenAlex.
- A photogenerated triplet aura-nitrene for gold-mediated nitrene transfer.Nature chemistry · 2026Article
- A gold nitrene for nitrogen-atom transfer chemistry.Nature chemistry · 2026Article
- Gold(III)-Substituted Carbenes.Journal of the American Chemical Society · 2026Article
- TheBeilstein journal of organic chemistry · 2026Article
- Synthesis of (P^N^C)Gold(III) Complexes via Tandem Oxidative Addition/C-H Auration.ACS organic & inorganic Au · 2025Article
- Mechanistic Insights into Molecular Oxygen Reactivity with Late Transition Metal-Hydride Bonds.Inorganic chemistry · 2025Article
- Interrogating theJACS Au · 2025Article
- Gold Tripyrrindione: Redox Chemistry and Reactivity with Dichloromethane.Inorganic chemistry · 2024Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A novel class of (P^N^C) pincer ligands capable of stabilizing elusive gold(III) species is reported here. Straightforward access to (P^N^C)gold(III) hydroxo, formate, and hydride complexes has been streamlined by first incorporating a cycloauration step devoid of toxic metals or harsh conditions. The resulting gold complexes exhibit remarkable stability in solution as well as in the solid state under ambient conditions, which enabled their characterization by X-ray diffraction analyses. Interestingly, the influence of the ligand allowed the preparation of gold(III)-hydrides using mild hydride donors such as H-Bpin, which contrasts with sensitive super hydrides or strong acids and cryogenic conditions employed in previous protocols. A detailed bonding characterization of these species is complemented by reactivity studies.
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Registered trials
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