ArticleNature communications2024
Highly defective ultra-small tetravalent MOF nanocrystals.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
19 citing papers in PubMed.
- Guiding the De Novo Synthesis of Open Metal Frameworks Through Low-Symmetry Bent Linker for Hydrogen Isotope Separation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Defect-Guided Assembly of Aperiodic and Flexible Metal-Organic Frameworks From Pre-Formed Cages.Angewandte Chemie (International ed. in English) · 2026Article
- ZrChemical science · 2026Article
- Ligand-Intercalated MOFs Enable Reaction-Pathway Engineering in Biomass Electrooxidation via Steric and π-Electronic Microenvironment Control.Angewandte Chemie (International ed. in English) · 2026Article
- UiO-66 metal-organic frameworks in biomedicine: From structural tunability to bioimaging, photodiagnostics, and photodynamic cancer therapy.FEBS open bio · 2026Review
- New Insights into Radical Mechanisms in Natural Drying Oils: Paint Binders as Reactors for Nanoparticle Formation.ACS omega · 2026Article
- In-situ growth of biomimetic ion-selective membranes via confined molecular encapsulation for superior fluoride/chloride separation.Nature communications · 2026Article
- Doxorubicin-Loaded Metal-Organic Framework for Ferroptosis-Enhanced Chemotherapy Through Sustained Zn Release and Glutathione Peroxidase Downregulation.Advanced healthcare materials · 2026Article
- Rapid Electrodeposition of Defect-Tuned MOF Nanoarchitectures: Synergistic Unlocking Electrochemical Performance via Dual Modulation of Morphology and Electronic Structure.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Lipid-Engineered Small-Sized Metal-Organic Frameworks for Targeted Delivery of Anlotinib in Lung Cancer Treatment.International journal of nanomedicine · 2026Article
- Mechanistic Insights into theJournal of the American Chemical Society · 2025Article
- Synthetic Aspects and Characterization Needs in MOF Chemistry - from Discovery to Applications.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Beyond Density: Unveiling the Trade-Off in Catalytic Site Optimization Using Defect-Engineered UiO-66.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Targeted Selenite Adsorption Using Defective Fe-BTC: Effective in Acidic and Alkaline Conditions.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Diffusion-programmed catalysis in nanoporous material.Nature communications · 2025Article
- Precision-Engineered Construction of Proton-Conducting Metal-Organic Frameworks.Nano-micro letters · 2024Review
- A general flame aerosol route to kinetically stabilized metal-organic frameworks.Nature communications · 2024Article
- Superior and efficient performance of cost-effective MIP-202 catalyst over UiO-66-(COScientific reports · 2024Article
- Ultrasmall Functionalized UiO-66 Nanoparticle/Polymer Pebax 1657 Thin-Film Nanocomposite Membranes for Optimal COACS applied materials & interfaces · 2024Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
The size and defects in crystalline inorganic materials are of importance in many applications, particularly catalysis, as it often results in enhanced/emerging properties. So far, applying the strategy of modulation chemistry has been unable to afford high-quality functional Metal-Organic Frameworks (MOFs) nanocrystals with minimized size while exhibiting maximized defects. We report here a general sustainable strategy for the design of highly defective and ultra-small tetravalent MOFs (Zr, Hf) crystals (ca. 35% missing linker, 4-6 nm). Advanced characterizations have been performed to shed light on the main factors governing the crystallization mechanism and to identify the nature of the defects. The ultra-small nanoMOFs showed exceptional performance in peptide hydrolysis reaction, including high reactivity, selectivity, diffusion, stability, and show emerging tailorable reactivity and selectivity towards peptide bond formation simply by changing the reaction solvent. Therefore, these highly defective ultra-small M(IV)-MOFs particles open new perspectives for the development of heterogeneous MOF catalysts with dual functions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.