ArticleBioresources and bioprocessing2022
Enzymatic synthesis of a novel solid-liquid phase change energy storage material based on levulinic acid and 1,4-butanediol.
Article in Bioresources and bioprocessing, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Facile Ester-based Phase Change Materials Synthesis for Enhanced Energy Storage Toward Battery Thermal Management.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Multistage Porous Carbon Derived from Enzyme-Treated Waste Walnut Green Husk and Polyethylene Glycol for Phase Change Energy Storage.Materials (Basel, Switzerland) · 2024Article
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7 authors.
Funding
Abstract
The current energy crisis has prompted the development and utilization of renewable energy and energy storage material. In this study, levulinic acid (LA) and 1,4-butanediol (BDO) were used to synthesize a novel levulinic acid 1,4-butanediol ester (LBE) by both enzymatic and chemical methods. The enzymatic method exhibited excellent performance during the synthesis process, and resulted in 87.33% of LBE yield, while the chemical method caused more by-products and higher energy consumption. What's more, the thermal properties of the obtained LBE as a phase change material (PCM) were evaluated. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed that the melting temperature, latent heat of melting, and pyrolysis temperature were 50.51 °C, 156.1 J/g, and 150-160 °C, respectively. Compared with the traditional paraffin, the prepared PCM has a superior phase transition temperature, a higher latent heat of melting, and better thermal stability. The thermal conductivity could be increased to 0.34 W/m/k after adding expanded graphite (EG). In summary, LBE has great potential in the application of energy storage as a low-temperature phase change energy storage material.
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