ArticleACS nanoscience Au2024
Sterically Selective [3 + 3] Cycloaromatization in the On-Surface Synthesis of Nanographenes.
Article in ACS nanoscience Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces.Angewandte Chemie (International ed. in English) · 2026Article
- Topology and peripheral functionality govern intramolecular π-π stacking, solid-state self-assembly and chiroptical activity in rigid bilayer nanographenes.Chemical science · 2026Article
- A saddle-shaped OBO-doped nanographene: facile synthesis, adaptive double-layer assembly, and enhanced Lewis acidity.Chemical science · 2026Article
- Accelerating discovery across scientific disciplines through reproducible workflows with AiiDAlab.Digital discovery · 2026Article
- The effect of lateral π-extension on azulene-based molecules on surface studied by LT-STM.Scientific reports · 2026Article
- Topological classification of cycloadditions occurring on-surface and in the solid-state.Communications chemistry · 2025Article
Corrections and comments
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Authors and funding
17 authors.
Funding
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Abstract
Surface-catalyzed reactions have been used to synthesize carbon nanomaterials with atomically predefined structures. The recent discovery of a gold surface-catalyzed [3 + 3] cycloaromatization of isopropyl substituted arenes has enabled the on-surface synthesis of arylene-phenylene copolymers, where the surface activates the isopropyl substituents to form phenylene rings by intermolecular coupling. However, the resulting polymers suffered from undesired cross-linking when more than two molecules reacted at a single site. Here we show that such cross-links can be prevented through steric protection by attaching the isopropyl groups to larger arene cores. Upon thermal activation of isopropyl-substituted 8,9-dioxa-8a-borabenzo[
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Registered trials
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