ArticleInorganic chemistry2024
Mechanistic Insights into Electrocatalytic Hydrogen Evolution by an Exceptionally Stable Cobalt Complex.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed, 16 citations in OpenAlex.
- Article
- Effects of Ligand Electronic Environment on Electrocatalytic Proton Reduction by Cobalt Complexes.Chemistry, an Asian journal · 2026Article
- Unveiling the Potential ofJournal of the American Chemical Society · 2026Article
- Bioinspired Copper(II) Complexes With N,S-Donor Ligands: Structure-Activity Relationships and Mechanistic Insights for Aqueous Hydrogen Evolution Reaction.ChemSusChem · 2026Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Co(aPPy) is one of the most stable and active molecular first-row transition-metal catalysts for proton reduction reported to date. Understanding the origin of its high performance via mechanistic studies could aid in developing even better catalysts. In this work, the catalytic mechanism of Co(aPPy) was electrochemically probed, in both organic solvents and water. We found that different mechanisms can occur depending on the solvent and the acidity of the medium. In organic solvent with a strong acid as the proton source, catalysis initiates directly after a single-electron reduction of Co
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Registered trials
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