Simple and Green Preparation of Tetraalkoxydiborons and Diboron Diolates from Tetrahydroxydiboron.

Ryan M Fornwald, Anshu Yadav, Jose R Montero Bastidas, Milton R Smith, Robert E Maleczka

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Article in The Journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

5 authors.

Ryan M FornwaldDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48824, United States.

Anshu YadavDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48824, United States.ORCID 0000-0001-7233-2280

Jose R Montero BastidasDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48824, United States.ORCID 0000-0002-6325-8565

Milton R SmithDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48824, United States.ORCID 0000-0002-8036-4503

Robert E MaleczkaDepartment of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48824, United States.ORCID 0000-0002-1119-5160

Funding

Metal-Catalyzed C-H Borylation: Mechanism, Scope, and ApplicationsR01GM063188 · NIGMS · MICHIGAN STATE UNIVERSITY · PI SMITH, MILTON RUDOLPH · 2001 to 2020

$3.4M

Metal-Catalyzed C-H Borylation: Mechanism, Scope, and ApplicationsR56GM063188 · NIGMS · MICHIGAN STATE UNIVERSITY · PI SMITH, MILTON R · 2007 to 2007

$236k

NIGMS NIH HHS R01 GM063188NIGMS NIH HHS R56 GM063188

6 · The paper itself

Abstract

Tetraalkoxydiborons can be easily prepared by acid-catalyzed reactions of tetrahydroxydiboron or its anhydride with trialkyl orthoformates. Addition of diols to these reaction mixtures afforded diboron diolates in high yield. In both cases, removal of volatile byproducts is all that is required for the isolation of the diboron. These methods constitute a convenient alternative to previous preparations from tetrakis (dimethylamino) diboron and tetrahydroxydiboron.

Identifiers

PMID38640193

DOI10.1021/acs.joc.3c02992

PMCPMC11077490

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LicenceCC BY

Read underepoch 390

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.