A comparative study of electropolymerization and photopolymerization for the determination of molnupiravir and their application in an electrochemical sensor via computationally designed molecularly imprinted polymers.

Ahmet Cetinkaya, M Altay Unal, Hasan Nazır, M Emin Çorman, Lokman Uzun, Sibel A Ozkan

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Article in Mikrochimica acta, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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0 citing papers in PubMed, 13 citations in OpenAlex.

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5 · Who and what money

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6 authors at 3 institutions in 1 country.

Ahmet CetinkayaFaculty of Pharmacy, Department of Analytical Chemistry, Ankara University, Ankara, Turkey.

M Altay UnalStem Cell Institute, Ankara University, Ankara, Turkey.

Hasan NazırFaculty of Science, Department of Chemistry, Ankara University, Ankara, Turkey.

M Emin ÇormanGülhane Faculty of Pharmacy, Department of Biochemistry, University of Health Sciences, Ankara, Turkey.

Lokman UzunFaculty of Science, Department of Chemistry, Hacettepe University, Ankara, Turkey.

Sibel A OzkanFaculty of Pharmacy, Department of Analytical Chemistry, Ankara University, Ankara, Turkey. sibel.ozkan@pharmacy.ankara.edu.tr.ORCID http://orcid.org/0000-0001-7494-3077

Ankara University · TRHacettepe University · TRSağlık Bilimleri Üniversitesi · TR

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A comparative analysis of molecularly imprinted polymers based on different synthesis techniques was performed for the recognition of molnupiravir (MOL). The polymerizations were performed with 3-thienyl boronic acid (3-TBA) as a functional monomer by electropolymerization (EP) and with guanine methacrylate (GuaM) as a functional monomer by photopolymerization (PP). Morphological and electrochemical characterizations of the developed sensors were investigated to verify the constructed sensors. Moreover, quantum chemical calculations were used to evaluate changes on the electrode surface at the molecular and electronic levels. The dynamic linear range of both designed sensors under optimized experimental conditions was found to be 7.5 × 10

Indexed as

Boronic AcidsHydroxylaminesMolecularly Imprinted PolymersCytidineElectrodesGuanineMethacrylatesReproducibility of ResultsBoronic AcidsCytidineGuanineHydroxylaminesMethacrylatesMolecularly Imprinted PolymersmolnupiravirDifferential pulse voltammetryElectropolymerizationModified electrodeMolecularly imprinted polymerMolnupiravirPhotopolymerization

Identifiers

PMID38630200

DOI10.1007/s00604-024-06353-w

PMCPMC11024036

OpenAlexW4394873154

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.