ArticleNature communications2024
Solvent-free selective hydrogenation of nitroaromatics to azoxy compounds over Co single atoms decorated on Nb
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- RuNature communications · 2026Article
- Metal-mediated weak adsorption enables the selective electrosynthesis of N-phenylhydroxylamine from nitrobenzene hydrogenation in water.Nature communications · 2026Article
- WAngewandte Chemie (International ed. in English) · 2026Article
- Low-Temperature CHNano-micro letters · 2026Article
- Synergistic non-bonding diatomic Pt sites for efficient hydrogenation of nitro compounds.Nature communications · 2026Article
- Biocatalytic reduction of nitro-sulfonamides: enzyme engineering, process integration, and sustainable pathways toFrontiers in bioengineering and biotechnology · 2026Review
- Site-specific synergy by heteronuclear microenvironment atomic editing for oxygen reduction reaction.Nature communications · 2025Article
- Site-specific synergy in heterogeneous single atoms for efficient oxygen evolution.Nature communications · 2025Article
- Structure-activity relationships in the development of single atom catalysts for sustainable organic transformations.Nanoscale advances · 2025Review
- Unspecific peroxygenase enabled formation of azoxy compounds.Nature communications · 2024Article
Corrections and comments
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Authors and funding
14 authors.
Funding
Abstract
The solvent-free selective hydrogenation of nitroaromatics to azoxy compounds is highly important, yet challenging. Herein, we report an efficient strategy to construct individually dispersed Co atoms decorated on niobium pentaoxide nanomeshes with unique geometric and electronic properties. The use of this supported Co single atom catalysts in the selective hydrogenation of nitrobenzene to azoxybenzene results in high catalytic activity and selectivity, with 99% selectivity and 99% conversion within 0.5 h. Remarkably, it delivers an exceptionally high turnover frequency of 40377 h
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Registered trials
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