ArticleThe Journal of organic chemistry2024
The Development of a Sulfamate-Tethered Aza-Michael Cyclization Allows for the Preparation of (-)-Negamycin
Article in The Journal of organic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Negamycin: Nature's Forgotten Antibiotic.ACS infectious diseases · 2026Review
- Syntheses of Natural and Non-Natural β-Amino Acids Using Racemic and Enantioselective Sulfamate-TetheredTetrahedron · 2025Article
- Transformation of Linear AlkenylChemistry (Basel, Switzerland) · 2025Article
- Stereoselective Preparation of (Molbank · 2025Article
- A Catalytic, Enantioselective Sulfamate TetheredOrganic letters · 2024Article
- Exploration of One-Pot, Tandem Sulfamoylation andThe Journal of organic chemistry · 2024Article
- Taming Tethered Nitreniums for Alkene Functionalization Reactions.The Journal of organic chemistry · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
We present the first examples of intramolecular aza-Michael cyclizations of sulfamates and sulfamides onto pendant α,β-unsaturated esters, thioesters, amides, and nitriles. Stirring the substrate with catalytic quantities of the appropriate base delivers the product in good yield and excellent diastereoselectivity. The reactions are operationally simple, can be performed open to air, and are tolerant of a variety of important functional groups. We highlight the utility of this technology by using it in the preparation of a (-)-negamycin derivative.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.