ArticleInorganic chemistry2024
Impact of Surface Ligand Identity and Density on the Thermodynamics of H Atom Uptake at Polyoxovanadate-Alkoxide Surfaces.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Evidence for Site-Specific Tunneling in H Atom Uptake at the Surface of Polyoxovanadate-Alkoxides.JACS Au · 2026Article
- Redox-State-Driven Site Selectivity and Kinetic Gating in Polyoxovanadate Methylation.Inorganic chemistry · 2026Article
- Ensemble Effects on Hydroxide Bond Dissociation Free Energies in Polyoxovanadate Clusters.The journal of physical chemistry. A · 2026Article
- Morphology Effects on Free Energies of Proton-Coupled Electron Transfer in Polyoxotungstates.Inorganic chemistry · 2025Article
- Electrochemically Determined and Structurally Justified Thermochemistry of H atom Transfer on Ti-Oxo Nodes of the Colloidal Metal-Organic Framework Ti-MIL-125.Journal of the American Chemical Society · 2024Article
- Vanadium Substitution Dictates H Atom Uptake at Lindqvist-type Polyoxotungstates.Inorganic chemistry · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
An understanding of how molecular structure influences the thermodynamics of H atom transfer is critical to designing efficient catalysts for reductive chemistries. Herein, we report experimental and theoretical investigations summarizing structure-function relationships of polyoxovanadate-alkoxides that influence bond dissociation free energies of hydroxide ligands located at the surface of the cluster. We evaluate the thermochemical descriptors of O-H bond strength for a series of clusters, namely [V
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Registered trials
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