Evidence map›Paper›PMID 38569515›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024

Torsion Effects Beyond the δ Bond and the Role of π Metal-Ligand Interactions.

Almudena Inchausti, Rosa Mollfulleda, Marcel Swart, Josefina Perles, Santiago Herrero, Valentín G Baonza, Mercedes Taravillo, Álvaro Lobato

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Torsion Effects Beyond the δ Bond and the Role of π Metal-Ligand Interactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Almudena InchaustiMALTA-Consolider Team and Departamento de Química Física, Universidad Complutense de Madrid, Plz. Ciencias 2, Madrid, E-28040, Spain.ORCID https://orcid.org/0000-0002-1518-0687
Rosa MollfulledaInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Campus de Montilivi, Parc UdG, Catalonia, Girona, E-17003, Spain.ORCID https://orcid.org/0000-0003-0199-9883
Marcel SwartInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Campus de Montilivi, Parc UdG, Catalonia, Girona, E-17003, Spain.ORCID https://orcid.org/0000-0002-8174-8488
Josefina PerlesLaboratorio de Difracción de Rayos X de Monocristal, Servicio Interdepartamental de Investigación, Universidad Autónoma de Madrid, Madrid, E-28049, Spain.ORCID https://orcid.org/0000-0003-0256-0186
Santiago HerreroMatMoPol Research Group, Departamento de Química Inorgánica, Universidad Complutense de Madrid, Plz. Ciencias 2, Madrid, E-28040, Spain.ORCID https://orcid.org/0000-0002-9901-1142
Valentín G BaonzaMALTA-Consolider Team and Departamento de Química Física, Universidad Complutense de Madrid, Plz. Ciencias 2, Madrid, E-28040, Spain.ORCID https://orcid.org/0000-0001-9994-0980
Mercedes TaravilloMALTA-Consolider Team and Departamento de Química Física, Universidad Complutense de Madrid, Plz. Ciencias 2, Madrid, E-28040, Spain.ORCID https://orcid.org/0000-0003-1159-8530
Álvaro LobatoMALTA-Consolider Team and Departamento de Química Física, Universidad Complutense de Madrid, Plz. Ciencias 2, Madrid, E-28040, Spain.ORCID https://orcid.org/0000-0002-2798-6178

Funding

Agencia Estatal de Investigación PID2020-114548GB-I00Agencia Estatal de Investigación PID2021-122585NB-C22Agencia Estatal de Investigación PRE2021-097669Agencia Estatal de Investigación RED2022-134388-TUCM GRFN32/23
6 · The paper itself

Abstract

Previous studies on bimetallic paddlewheel compounds have established a direct correlation between metal-metal distance and ligand torsion angles, leading to the rule that higher torsion results in longer metal-metal bond distances. Here, the new discovery based on diarylformamidinate Ru₂⁵⁺ paddlewheel compounds [Ru

Indexed as

bidentate ligandsdirutheniumelectronic structuremetal–metal bondpaddlewheel

Identifiers

PMID38569515
PMCPMC11220682

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.