ArticleAngewandte Chemie (International ed. in English)2024
Supertwisted Chiral Gyroid Mesophase in Chiral Rod-Like Compounds.
Article in Angewandte Chemie (International ed. in English), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed, 13 citations in OpenAlex.
- Structural Complexity, Network Formation and Spontaneous Chirality in Soft-Matter Self-Assembly.Accounts of chemical research · 2026Article
- Unraveling hidden symmetry breaking in racemic compounds.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Geometry Controls Confined Water Dynamics in Lipidic Mesophases.Angewandte Chemie (International ed. in English) · 2026Article
- Gyroid Labyrinth of Supertwisted Double Helices in a Liquid Crystal Polymer.Angewandte Chemie (International ed. in English) · 2026Article
- On the Mechanism of Soft Self-Assembly from Melt: The Ubiquitous Heat Capacity Hump and Spontaneous Melt Chirality.Angewandte Chemie (International ed. in English) · 2025Article
- Supertwisted Chiral Gyroid Mesophase in Chiral Rod-Like Compounds.Angewandte Chemie (International ed. in English) · 2024Article
Corrections and comments
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Authors and funding
8 authors at 4 institutions in 3 countries.
Funding
Abstract
Among the intriguing bicontinuous self-assembled structures, the gyroid cubic is the most ubiquitous. It is found in block and star polymers, surfactants with or without solvent, in thermotropic liquid crystals with end- or side-chains, and in biosystems providing structural color and modelling cell mitosis. It contains two interpenetrating networks of opposite chirality and is thus achiral if, as usual, the content of the two nets is the same. However, we now find that this is not the case for strongly chiral compounds. While achiral molecules follow the opposite twists of nets 1 and 2, molecules with a chiral center in their rod-like core fail to follow the 70° twist between junctions in net 2 and instead wind against it by -110° to still match the junction orientation. The metastable chiral gyroid is a high-entropy high-heat-capacity mesophase. The homochirality of its nets makes the CD signal of the thienofluorenone compounds close to that in the stable I23 phase with 3 isochiral nets.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.